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    Home > IODOMETHANE-D3 SDS

    IODOMETHANE-D3 Safety Data Sheets

    SAFETY DATA SHEETS

    According to the UN GHS revision 8

    Version: 1.0

    Creation Date: July 15, 2019

    Revision Date: July 15, 2019

    SECTION 1: Identification

    1.1 GHS Product identifier

    Product name

    Iodo(2H3)methane

    1.2 Other means of identification

    Product number

    -

    Other names

    Methyl-d3 Iodide;trideuterioiodomethane;Methyl-12C,d3 iodide

    1.3 Recommended use of the chemical and restrictions on use

    Identified uses

    Industrial and scientific research uses.

    Uses advised against

    no data available

    1.4 Supplier's details

    Company

    Echemi.com

    Address

    Echemi.com

    Telephone

    Echemi.com

    1.5 Emergency phone number

    Emergency phone number

    Echemi.com

    Service hours

    Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

    SECTION 2: Hazard identification

    2.1 Classification of the substance or mixture

    Acute toxicity - Category 3, Oral

    Acute toxicity - Category 4, Dermal

    Skin irritation, Category 2

    Skin sensitization, Category 1

    Acute toxicity - Category 3, Inhalation

    Respiratory sensitization, Category 1

    Carcinogenicity, Category 2

    Specific target organ toxicity – single exposure, Category 2

    2.2 GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H301+H331 Toxic if swallowed or if inhaled

    H312 Harmful in contact with skin

    H315 Causes skin irritation

    H317 May cause an allergic skin reaction

    H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled

    H335 May cause respiratory irritation

    H351 Suspected of causing cancer

    H371 May cause damage to organs

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P270 Do not eat, drink or smoke when using this product.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

    P272 Contaminated work clothing should not be allowed out of the workplace.

    P271 Use only outdoors or in a well-ventilated area.

    P284 [In case of inadequate ventilation] wear respiratory protection.

    P203 Obtain, read and follow all safety instructions before use.

    P260 Do not breathe dust/fume/gas/mist/vapours/spray.

    Response

    P301+P316 IF SWALLOWED: Get emergency medical help immediately.

    P321 Specific treatment (see ... on this label).

    P330 Rinse mouth.

    P302+P352 IF ON SKIN: Wash with plenty of water/...

    P317 Get medical help.

    P362+P364 Take off contaminated clothing and wash it before reuse.

    P332+P317 If skin irritation occurs: Get medical help.

    P333+P317 If skin irritation or rash occurs: Get medical help.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P316 Get emergency medical help immediately.

    P342+P316 If experiencing respiratory symptoms: Get emergency medical help immediately.

    P318 IF exposed or concerned, get medical advice.

    P308+P316 IF exposed or concerned: Get emergency medical help immediately.

    Storage

    P405 Store locked up.

    P403+P233 Store in a well-ventilated place. Keep container tightly closed.

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    2.3 Other hazards which do not result in classification

    no data available

    SECTION 3: Composition/information on ingredients

    3.1 Substances

    Chemical name Common names and synonyms CAS number EC number Concentration
    Iodo(2H3)methane Iodo(2H3)methane 865-50-9 212-744-5 100%

    SECTION 4: First-aid measures

    4.1 Description of necessary first-aid measures

    If inhaled

    Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

    Following skin contact

    Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

    Following eye contact

    Rinse with pure water for at least 15 minutes. Consult a doctor.

    Following ingestion

    Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

    4.2 Most important symptoms/effects, acute and delayed

    no data available

    4.3 Indication of immediate medical attention and special treatment needed, if necessary

    no data available

    SECTION 5: Fire-fighting measures

    5.1 Suitable extinguishing media

    Use dry chemical, carbon dioxide or alcohol-resistant foam.

    5.2 Specific hazards arising from the chemical

    no data available

    5.3 Special protective actions for fire-fighters

    Wear self-contained breathing apparatus for firefighting if necessary.

    SECTION 6: Accidental release measures

    6.1 Personal precautions, protective equipment and emergency procedures

    Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.

    6.2 Environmental precautions

    Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.

    6.3 Methods and materials for containment and cleaning up

    Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

    SECTION 7: Handling and storage

    7.1 Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    7.2 Conditions for safe storage, including any incompatibilities

    Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

    SECTION 8: Exposure controls/personal protection

    8.1 Control parameters

    Occupational Exposure limit values

    no data available

    Biological limit values

    no data available

    8.2 Appropriate engineering controls

    Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

    8.3 Individual protection measures, such as personal protective equipment (PPE)

    Eye/face protection

    Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).

    Skin protection

    Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

    Respiratory protection

    If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.

    Thermal hazards

    no data available

    SECTION 9: Physical and chemical properties and safety characteristics

    Physical state

    colourless liquid

    Colour

    no data available

    Odour

    no data available

    Melting point/freezing point

    -66.5ºC(lit.)

    Boiling point or initial boiling point and boiling range

    42ºC

    Flammability

    no data available

    Lower and upper explosion limit/flammability limit

    no data available

    Flash point

    none

    Auto-ignition temperature

    no data available

    Decomposition temperature

    no data available

    pH

    no data available

    Kinematic viscosity

    no data available

    Solubility

    no data available

    Partition coefficient n-octanol/water

    no data available

    Vapour pressure

    no data available

    Density and/or relative density

    2.32

    Relative vapour density

    no data available

    Particle characteristics

    no data available

    SECTION 10: Stability and reactivity

    10.1 Reactivity

    no data available

    10.2 Chemical stability

    no data available

    10.3 Possibility of hazardous reactions

    no data available

    10.4 Conditions to avoid

    no data available

    10.5 Incompatible materials

    no data available

    10.6 Hazardous decomposition products

    no data available

    SECTION 11: Toxicological information

    Acute toxicity

    • Oral: no data available
    • Inhalation: no data available
    • Dermal: no data available

    Skin corrosion/irritation

    no data available

    Serious eye damage/irritation

    no data available

    Respiratory or skin sensitization

    no data available

    Germ cell mutagenicity

    no data available

    Carcinogenicity

    no data available

    Reproductive toxicity

    no data available

    STOT-single exposure

    no data available

    STOT-repeated exposure

    no data available

    Aspiration hazard

    no data available

    SECTION 12: Ecological information

    12.1 Toxicity

    • Toxicity to fish: no data available
    • Toxicity to daphnia and other aquatic invertebrates: no data available
    • Toxicity to algae: no data available
    • Toxicity to microorganisms: no data available

    12.2 Persistence and degradability

    no data available

    12.3 Bioaccumulative potential

    no data available

    12.4 Mobility in soil

    no data available

    12.5 Other adverse effects

    no data available

    SECTION 13: Disposal considerations

    13.1 Disposal methods

    Product

    The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

    Contaminated packaging

    Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

    SECTION 14: Transport information

    14.1 UN Number

    ADR/RID: UN2644 (For reference only, please check.) IMDG: UN2644 (For reference only, please check.) IATA: UN2644 (For reference only, please check.)

    14.2 UN Proper Shipping Name

    ADR/RID: METHYL IODIDE (For reference only, please check.) IMDG: METHYL IODIDE (For reference only, please check.) IATA: METHYL IODIDE (For reference only, please check.)

    14.3 Transport hazard class(es)

    ADR/RID: 6.1 (For reference only, please check.) IMDG: 6.1 (For reference only, please check.) IATA: 6.1 (For reference only, please check.)

    14.4 Packing group, if applicable

    ADR/RID: I (For reference only, please check.) IMDG: I (For reference only, please check.) IATA: I (For reference only, please check.)

    14.5 Environmental hazards

    ADR/RID: No IMDG: No IATA: No

    14.6 Special precautions for user

    no data available

    14.7 Transport in bulk according to IMO instruments

    no data available

    SECTION 15: Regulatory information

    15.1 Safety, health and environmental regulations specific for the product in question

    Chemical name Common names and synonyms CAS number EC number
    Iodo(2H3)methane Iodo(2H3)methane 865-50-9 212-744-5
    European Inventory of Existing Commercial Chemical Substances (EINECS) Listed.
    EC Inventory Listed.
    United States Toxic Substances Control Act (TSCA) Inventory Not Listed.
    China Catalog of Hazardous chemicals 2015 Not Listed.
    New Zealand Inventory of Chemicals (NZIoC) Listed.
    Philippines Inventory of Chemicals and Chemical Substances (PICCS) Not Listed.
    Vietnam National Chemical Inventory Not Listed.
    Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) Not Listed.
    Korea Existing Chemicals List (KECL) Not Listed.

    SECTION 16: Other information

    Information on revision

    Creation Date July 15, 2019
    Revision Date July 15, 2019

    Abbreviations and acronyms

    • CAS: Chemical Abstracts Service
    • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
    • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
    • IMDG: International Maritime Dangerous Goods
    • IATA: International Air Transportation Association
    • TWA: Time Weighted Average
    • STEL: Short term exposure limit
    • LC50: Lethal Concentration 50%
    • LD50: Lethal Dose 50%
    • EC50: Effective Concentration 50%

    References

    • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
    • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
    • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
    • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
    • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
    • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
    • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
    • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
    • ECHA - European Chemicals Agency, website: https://echa.europa.eu/
    Any questions regarding this SDS, Please send your inquiry to sds@xixisys.com

    Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.

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