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fluoroboric Acid

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CAS No.:

16872-11-0

Grade:

Plating Grade

Port:

QINGDAO

Packaging:

25kg/1.5kg White HDPE Drum (Used For PA)

Price valid (until):

2017-02-16

Company Type:
Manufactory
Location:
China
Qualification:
Main Products:

Ammonium fluoroborate ,Bismuth methane sulfonate ,copper fluoroborate ,Copper methane sulfonate ,lead fluoroborate ,Lead methyl sulfonate

  • Product Description

  • Seller Information

  • Inquiry History

  • Description

    Molecular formula: HBF4
    Relative molecular weight: 87.81
    CAS NO: 16872-11-0
    Executive standard: Q/HD04-2005

    Item
    Index
    Index
    Fluoroboric acid (HBF4), % ≥
    49.5
    49.5
    Free boric acid, % ≤
    2.5
    2.5
    Iron (Fe), % ≤
    0.005
    0.005
    Chloride, % ≤
    0.005
    0.005
    Sulfate, % ≤
    0.003
    0.01
    Pb  %  ≤----0.005

     

    Properties: Colorless transparent liquid; relative density is about 1.37; blendable and soluble in water and alcohol; decompose when heated to 130℃; can react with metallic element, metallic fluoride, oxide, hydroxid or carbonate to produce corresponding fluoborate; toxic.

    Use: Fluoroboric acid is the main component of electroplate liquid. It can be used as catalyst for alkylation and polymerization, and is the material to make various fluoborate. Its 2.5% solution can be used to electrolytically polish pure aluminum. Moreover, it can be used to clean and corrode metal surface oxide and silicate film.

    Packing: Pack in 6kg, 25kg, 30kg or 250kg polyvinyl plastic drum.


    Basic Info
    Product Name:

    Tetrafluoroboric acid

    Other Name:

    Borate(1-),tetrafluoro-,hydrogen (1:1);Borate(1-),tetrafluoro-,hydrogen;Fluoboric acid (HBF4);Fluoroboric acid;Hydrogen tetrafluoroborate;HBF4;Tetrafluoroboric acid;Hydrogen tetrafluoroborate(1-);Borofluoric acid;1303-67-9;13767-36-7;36835-64-0;65814-43-9;67116-13-6;72802-72-3;74618-51-2;81586-24-5;96958-96-2;102931-96-4;122141-73-5;127408-00-8;133097-00-4;133951-38-9;140148-87-4;172515-29-6;172908-18-8;183135-74-2;191665-41-5;350009-05-1;496925-14-5;547767-06-6;845825-70-9;900178-90-7;1056477-09-8;1178564-64-1;1262801-47-7;1414852-51-9;1631149-30-8

    CAS No.:

    16872-11-0

    UN No.:

    1775

    Molecular Formula:

    BF4.H

    InChIKeys:

    InChIKey=ODGCEQLVLXJUCC-UHFFFAOYSA-O

    Molecular Weight:

    87.81260

    Exact Mass:

    88.01070

    EC Number:

    240-898-3

    UNII:

    H429WZ9FBQ

    ICSC Number:

    1040

    UN Number:

    1775

    DSSTox ID:

    DTXSID8029739

    Color/Form:

    Colorless liquid

    HScode:

    2811199090

    Categories:

    Inorganic Salts

    Characteristics
    PSA:

    0

    XLogP3:

    1.41250

    Appearance:

    Fluoroboric acid appears as a colorless odorless poisonous liquid. Corrosive to metals and tissue. It is used in electroplating, metal cleaning and making diazo salts.

    Density:

    1.84 g/cm3 (approx)

    Melting Point:

    -90ºC

    Boiling Point:

    130ºC (dec.)

    Flash Point:

    -40 °F

    Refractive Index:

    Refractive index of a 20% aqueous solution: 1.3284 at 20 °C/D

    Water Solubility:

    Very soluble in water, ethanol

    Storage Conditions:

    Pure HBF4 (fluoroboric acid) may be stored in glass vessels at room temperature.

    Vapor Pressure:

    39100mmHg at 25°C

    Dissociation Constants:

    pKa: -4.9

    Experimental Properties:

    Heat of formation: 388.5 kcal; undergoes limited hydrolysis in water to form hydroxyfluoborate ions; major product is BF3OH- ion; forms crystalline salts with metals|Heat of formation (aqueous, 1 molal at 25 °C): -1527 kJ/mol; specific gravity (48% solution): 1.37; specific gravity (42% solution): 1.32; specific gravity (30% solution): 1.20; surface tension (48% solution at 25 °C): 65.3 mN/m|Fluoroboric acid does not exist as a free, pure substance; the acid is only stable as the solvated ion pair, such as H3O+BF4-

    Air and Water Reactions:

    Soluble in water with release of heat.

    Reactive Group:

    Acids, Strong Non-oxidizing

    Reactivity Alerts:

    Known Catalytic Activity

    Reactivity Profile:

    FLUOROBORIC ACID is a strong acid. Reacts exothermically with chemical bases (examples: amines, amides, and inorganic hydroxides). These reactions can generate dangerously large amounts of heat in small spaces. Dissolution in water or the dilution of a concentrated aqueous solution may generate significant heat. Reacts with active metals, including such structural metals as aluminum and iron, to release hydrogen, a flammable gas. Can initiate the polymerization of certain alkenes. Reacts with cyanide compounds to release gaseous hydrogen cyanide. Generates flammable and/or toxic gases in contact with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and strong reducing agents. Additional gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and carbonates. May catalyze (increase the rate of) chemical reactions. Attempted drying of the acid with acetic anhydride caused an explosion at 0°C [J. Organomet. Chem., 1975, 94, 319].

    Hazard Identification

    Classification of the substance or mixture

    Skin corrosion, Sub-category 1B

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Danger

    Hazard statement(s)

    H314 Causes severe skin burns and eye damage

    Precautionary statement(s)
    Prevention

    P260 Do not breathe dust/fume/gas/mist/vapours/spray.

    P264 Wash ... thoroughly after handling.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    Response

    P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

    P363 Wash contaminated clothing before reuse.

    P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

    P316 Get emergency medical help immediately.

    P321 Specific treatment (see ... on this label).

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    Storage

    P405 Store locked up.

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Separated from strong bases, metals and food and feedstuffs. Well closed. Ventilation along the floor. Store only in original container. Do NOT store or transport in containers made from metal or glass. Store in an area without drain or sewer access.

  • Seller Information
    Business Type:

    Manufactory

    Location:

    Liudian, Economic Development Zone, Panlongcheng Wuhan city, China

  • Inquiry History
    2 Inquiries
    Country Product Purchase Quantity Date Posted
    France

    Fluoroboric acid 99% liquid 16872-11-0

    1 MT Sep 14, 2023
    Philippines

    Fluoroboric acid 99% liquid 16872-11-0 Dideu

    25 KG Nov 5, 2024
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