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Ethylenediamine-ethylenimine copolymer

Ethylenediamine-ethylenimine copolymer structure

Ethylenediamine-ethylenimine copolymer 

structure
  • CAS No:

    25987-06-8

  • Formula:

    (C2H8N2.C2H5N)x

  • Chemical Name:

    Ethylenediamine-ethylenimine copolymer

  • Synonyms:

    1,2-Ethanediamine,polymer with aziridine;Ethylenimine,polymer with ethylenediamine;Ethylenediamine,polymer with ethylenimine;Aziridine,polymer with 1,2-ethanediamine;Ethylenediamine-ethylenimine copolymer;Aziridine-ethylenediamine polymer;Ethylenediamine-ethylenimine polymer;Aziridine-1,2-diaminoethane copolymer;Aziridine-1,2-ethylenediamine copolymer

  • Categories:

    Catalyst and Auxiliary  >  Polymer

Description

Polyethyleneimines (PEIs) are highly basic and positively charged aliphatic polymers, containing primary, secondary and tertiary amino groups in a 1:2:1 ratio. Every third atom of the polymeric backbone is therefore an amino nitrogen that may undergo protonation. As the polymer contains repeating units of ethylamine, PEIs are also highly watersoluble. PEIs are available in both linear and branched forms with molecular weights ranging from 700 Da to 1000 kDa.
For a long time, PEI has been

Ethylenediamine-ethylenimine copolymer Basic Attributes

43.07 g/mol

43.042199 g/mol

205-793-9

3911900090

Characteristics

21.9 Ų

log Kow = -0.28 (est)

Ethyleneimine, stabilized appears as a clear colorless liquid with an ammonia-like odor. Flash point 12°F. Less dense than water. Flammable over a wide range of vapor-air concentrations. Vapors irritate the skin, eyes, nose, and throat. May be toxic by prolonged inhalation, skin absorption, or ingestion. Carcinogenic. Vapors heavier than air. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently.

1.08 g/mL at 25 °C

-98 °F Freezing Point (EPA, 1998)

131 to 133 °F at 760 mm Hg (EPA, 1998)

>230 °F

n20/D 1.5240

Miscible (NIOSH, 2016)

9 mm Hg ( 20 °C)

Pungent, ammonia-like odor

Strongly alkaline

Safety Information

3

22-36-52/53-43-41

26-36-61-36/37/39

Xn

P273; P280; P305 + P351 + P338

H302; H317; H318; H412

|Danger|H302 (99.88%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P272, P273, P280, P301+P312, P302+P352, P305+P351+P338, P310, P321, P330, P333+P313, P337+P313, P363, P391, and P501|Aggregated GHS information provided by 905 companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Ethylenediamine-ethylenimine copolymer Use and Manufacturing

Uses

Detergents, adhesives, water treatment, printing inks, dyes, cosmetics, and paper industry, adhesion promoter, lamination primer, fixative agent, flocculant, cationic dispersant, stability enhancer, surface activator, chelating agent, scavenger for aldehydes and oxides.

1,2-Ethanediamine, polymer with aziridine: ACTIVE|XU - indicates a substance exempt from reporting under the Chemical Data Reporting Rule, (40 CFR 711).

Computed Properties

Molecular Weight:103.17
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:103.110947427
Monoisotopic Mass:103.110947427
Topological Polar Surface Area:74
Heavy Atom Count:7
Complexity:16.3
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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