Ethylenethiourea
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Ethylenethiourea
structure -
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CAS No:
96-45-7
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Formula:
C3H6N2S
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Chemical Name:
Ethylenethiourea
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Synonyms:
2-Imidazolidinethione;Imidazoline-2-thiol;Ethylenethiourea;N,N′-Ethylenethiourea;Warecure C;Thiourea,N,N′-1,2-ethanediyl-;NA 22;Tetrahydro-2H-imidazole-2-thione;Imidazoline-2(3H)-thione;2-Mercaptoimidazoline;Imidazolidinethione;Mercaptoimidazoline;2-Mercapto-2-imidazoline;2-Imidazoline-2-thiol;4,5-Dihydro-2-mercaptoimidazole;Rhodanin S 62;1,3-Ethylenethiourea;Pennac CRA;ETU;Mercazin I;Rhenogran ETU;Vulkacit NPV/C;Soxinol 22;Nocceler 22;2-Thioimidazolidine;Accel 22;Accel 22S;Sanceler 22;Sanceler 22C;2-Mercapto-4,5-dihydroimidazole;Ethylenethiocarbamide;ETC;END 75;Sanceler 22S;ETU 22S;ETU 80;Rhenogran ETU 80;TU 2;Sanmix 22-80E;Rhenogran ETU 75;ETU 75;Accelerator ETU;Accelerator NA 22;96-46-8;12261-94-8;26856-29-1;71836-04-9;90613-75-5;875479-38-2;1342300-13-3
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CAS No:
Description
Ethylene thiourea is a white to light green, needle-like crystalline solid with a faint amine odor. It is very soluble in hot water;slightly soluble in cold water, methanol, ethanol, ethylene glycol, pyridine, acetic acid, and naphtha; and insoluble in acetone, ether, chloroform, and benzene.When heated to decomposition, ethylene thiourea emits toxic fumes of nitrogen oxides (NOx) and sulfur oxides (SOx).
Ethylene thiourea is available in the United States as crystals, as a powder,
Characteristics
56.2
-0.66 (calculated)
White Powder
(at 20 °C): 1,26-1,28 g/cm³
199-204 °C
347.18 °C
252 °C
1.664
H2O: 19 g/L (20 ºC)
0-6°C
Vapour pressure, Pa at 25°C: 133
LD50 orally in rats: 1832 mg/kg (Graham, Hansen)
Combustible Solid
Faint, amine odor
Safety Information
III
6.1(b)
2811
2
61-22-48/23/25-40
53-45
NI9625000
T
Separated from strong oxidants. Store in an area without drain or sewer access.
Stable under normal temperatures and pressures.
P201, P202, P264, P270, P281, P301+P312, P308+P313, P330, P405, P501
H302
Ethylenethiourea Use and Manufacturing
Put 24 kg of ethylenediamine, 48 kg of industrial alcohol, and 60 kg of distilled water into the reactor in turn. Under stirring, slowly add 32 kg CS2, and control the temperature at about 60 ℃ during the dropwise addition. After the addition of CS2, the temperature was raised to 100 ℃ and refluxed for 1 h. Then add 3.6 kg concentrated hydrochloric acid and reflux for 9 to 10 hours. Cool crystallization. Suction filter was washed and dried with acetone to obtain product. The yield is about 80% to 85%.
Accelerator in synthetic rubber production.
Computed Properties
Molecular Weight:102.16
XLogP3:-0.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:1
Exact Mass:102.02516937
Monoisotopic Mass:102.02516937
Topological Polar Surface Area:56.2
Heavy Atom Count:6
Complexity:63.2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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