Bis[chloro(norbornadiene)rhodium]
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![Bis[chloro(norbornadiene)rhodium] structure](https://file.echemi.com/fileManage/upload/cas/13/5dd1d63e-3a02-40f4-a096-e4135794c09a.gif "Bis[chloro(norbornadiene)rhodium]")
Bis[chloro(norbornadiene)rhodium]
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CAS No:
12257-42-0
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Formula:
C14H16Cl2Rh2
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Chemical Name:
Bis[chloro(norbornadiene)rhodium]
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Synonyms:
Rhodium,bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorodi-;Rhodium,di-μ-chlorobis(2,5-norbornadiene)di-;Rhodium,dichlorobis(2,5-norbornadiene)di-;Bicyclo[2.2.1]hepta-2,5-diene,rhodium complex;Bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorodirhodium;Dichloro(norbornadiene)dirhodium;Rhodium norbornadiene chloride dimer;Bis[chloro(norbornadiene)rhodium];Norbornadiene rhodium chloride dimer;Chloronorbornadiene rhodium dimer;Bis((μ-chloro)(norbornadiene)rhodium);Bis(chloro(η4-norbornadiene)rhodium);(Bicyclo[2.2.1]hepta-2,5-diene)rhodium (I) chloride dimer;(η4-Norbornadiene)rhodium chloride dimer;Bis(μ-chloro)bis(norbornadiene)dirhodium;Bis((μ-chloro)(2,5-norbornadiene)rhodium);Di-μ-chlorobis(norbornadiene)dirhodium;Di-μ-chlorobis(η4-norbornadiene)dirhodium(I);Dichlorobis(norbornadiene)dirhodium;Bis(μ-chloro)bis[(norbornadiene)rhodium];12277-08-6;39357-17-0
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CAS No:
Characteristics
0
4.28560
yellow to orange Powder
240 °C (decomp)
89.5ºC at 760 mmHg
Slightly soluble in acetone, chloroform, methanol and insoluble in water.
2-8°C
66mmHg at 25°C
Safety Information
3
36/37/38
37/39-26
Xi,Xn
P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
H302
|Warning|H302 (14.29%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, and P501|Aggregated GHS information provided by 7 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Bis[chloro(norbornadiene)rhodium] Use and Manufacturing
Asymmetric catalytic cross-coupling reaction catalyst, hydrosilation catalyst
Computed Properties
Molecular Weight:358.1
Hydrogen Bond Acceptor Count:2
Exact Mass:356.96840
Monoisotopic Mass:356.96840
Heavy Atom Count:17
Complexity:103
Covalently-Bonded Unit Count:5
Compound Is Canonicalized:Yes
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Bis[chloro(norbornadiene)rhodium]
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