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Home > Encyclopedia > Allyl 2-(isopentyloxy)acetate

Allyl 2-(isopentyloxy)acetate

Allyl 2-(isopentyloxy)acetate structure

Allyl 2-(isopentyloxy)acetate 

structure
  • CAS No:

    67634-00-8

  • Formula:

    C10H18O3

  • Chemical Name:

    Allyl 2-(isopentyloxy)acetate

  • Synonyms:

    Acetic acid,2-(3-methylbutoxy)-,2-propen-1-yl ester;Acetic acid,(3-methylbutoxy)-,2-propenyl ester;Allyl 2-(isopentyloxy)acetate

  • Categories:

    Cosmetic Ingredient  >  Perfuming

Description

Allyl (3-Methylbutoxy)acetate is a colorless liquid of strong, fruity galbanum odor with pineapple modification. It can be prepared by reaction of chloroacetic acid with isoamyl alcohol in the presence of sodium hydroxide and a phase-transfer catalyst, then treating the resulting sodium amylglycolate with allyl alcohol. Allyl amylglycolate is used in fragrance compositions, for example, for detergents.


(3-methylbutoxy)acetic acid, 2-propenyl ester is a clear colorless liquid. (NTP, 1992)|Liquid


(3-methylbutoxy)acetic acid, 2-propenyl ester is a clear colorless liquid. (NTP, 1992)

Allyl 2-(isopentyloxy)acetate Basic Attributes

186.25

186.25

266-803-5

EMX89K493E

DTXSID9025580

2918990090

Characteristics

35.5

2.84

Clear colorless liquid.

0.941 at 68° F (NTP, 1992)

-23ºC

206-226 °C(lit.)

205 °F

1.432

less than 1 mg/mL at 68° F (NTP, 1992)

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Insoluble in water.

Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters

(3-METHYLBUTOXY)ACETIC ACID, 2-PROPENYL ESTER may react with strong oxidizing acids sufficiently exothermically to ignite the reaction products. Also generates heat with caustic solutions. May generate flammable hydrogen with alkali metals, hydrides, and other reducing agents.

Safety Information

2

36/37/38

26-36

AI8988000

Xi

P264, P270, P280, P301+P312, P302+P352, P321, P330, P332+P313, P362, P501

H302

This chemical is combustible. (NTP, 1992)

|Warning|H302 (97.71%): Harmful if swallowed [Warning Acute toxicity, oral]|P264, P270, P280, P301+P312, P302+P352, P321, P330, P332+P313, P362, and P501|Aggregated GHS information provided by 1749 companies from 12 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material under ambient temperatures. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is stored, weighed and diluted, wear an approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

Allyl 2-(isopentyloxy)acetate Use and Manufacturing

Uses

Used in the manufacture of daily fragrance


Odor agents


Air care products

Production

100,000 - 500,000 lb

All other chemical product and preparation manufacturing|Acetic acid, 2-(3-methylbutoxy)-, 2-propen-1-yl ester: ACTIVE

Computed Properties

Molecular Weight:186.25
XLogP3:2.3
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:8
Exact Mass:186.125594432
Monoisotopic Mass:186.125594432
Topological Polar Surface Area:35.5
Heavy Atom Count:13
Complexity:152
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

Material

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