(-)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate
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(-)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate
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CAS No:
39648-67-4
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Formula:
C20H13O4P
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Chemical Name:
(-)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate
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Synonyms:
Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin,4-hydroxy-,4-oxide,(11bR)-;Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin,4-hydroxy-,4-oxide,(R)-;(R)-(-)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate;(-)-4-Hydroxydinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin 4-oxide;(-)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate;(-)-1,1′-Dinaphthyl-2,2′-diyl hydrogen phosphate;(R)-(-)-BNDHP;(R)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate;(R)-1,1′-Bi-2-naphthol-2,2′-diyl hydrogen phosphate;(R)-(-)-Binaphthyl-2,2′-diyl hydrogen phosphate;(R)-BNPPA;(R)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate;(R)-1,1′-Binaphthalene-2,2′-diyl hydrogen phosphate;50574-62-4;1072908-83-8
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CAS No:
(-)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate Basic Attributes
349.3
348.29
4713363
-0
2909499000
Characteristics
55.8
4.8
white Powder
1.5±0.1 g/cm3
220 °C
619.5ºC at 760mmHg
328.5±26.8 °C
1.763
Solubility in hot Methanol, almost transparency.
Refrigerator
-607.5 º (c=1.4,MeOH)
Safety Information
3464
3
36/37/38-20/21/22
26-36-36/37/39-22
RZ2475100
Xi,Xn
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
H315
(-)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate Use and Manufacturing
Chiral ligand for hydrogen carboxylation reaction; for asymmetric Mannich reaction catalyzed by chiral Bronsted acid; for asymmetric dipole cycloaddition reaction with rhodium complexation and adjustment of diazo compounds; for Racemic amines that are difficult to separate; palladium derivatives have been used in asymmetric hydrogen carboxylation, and rhodium derivatives have been used in dipolar cycloaddition
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(-)-1,1′-Binaphthyl-2,2′-diyl hydrogen phosphate
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