Dicamba sodium salt

243.02

241.95100

217-846-3

4U752K13RR

3077

DTXSID8027450

49.4

1.36550

Sodium dicamba appears as solid crystals.

326.1ºC at 760 mmHg

151ºC

The solubility of the sodium salt of dicamba in water is about 40%.

8.98E-05mmHg at 25°C

Stable to oxidation and hydrolysis under conventional conditions. Resistant to acid and strong alkali. Vapor pressure 3.41X10-5 mmHg at 25 °C. Solubility at 25 °C per 100 ml solvent: ethanol 92.2 g, heavy aromatic naphthane solvent 5.2 g, water 0.65 g, xylene 7.8 g, diacetone alcohol 91.0 g, acetone 81.0 g, methylene chloride 26.0 g, cyclohexanone 91.6 g, pentane is insoluble. /Dicamba/

Water soluble.

Ethers

A carboxylic acid salt. It will behave as a weak base.

3077

P273, P501

H412

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. (ERG, 2016)

|Warning|H319 (42.38%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]|P264, P273, P280, P305+P351+P338, P337+P313, and P501|Aggregated GHS information provided by 210 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H412: Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]|P273, and P501

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: SMALL FIRE: Dry chemical, CO2, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Do not scatter spilled material with high-pressure water streams. Move containers from fire area if you can do it without risk. Dike fire-control water for later disposal. FIRE INVOLVING TANKS: Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Do not touch or walk through spilled material. Stop leak if you can do it without risk. Prevent dust cloud. Avoid inhalation of asbestos dust. SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later disposal. LARGE SPILL: Dike far ahead of liquid spill for later disposal. Cover powder spill with plastic sheet or tarp to minimize spreading. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic gases. Some liquids produce vapors that may cause dizziness or suffocation. Runoff from fire control may cause pollution. (ERG, 2016)

Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. (ERG, 2016)

Banvel SGF contains 23.15% sodium salt of dicamba (3,6-dichloro-o-anisic acid), 5.79% sodium salts of related acids, and 71.06% of inert ingredients.

Pesticide, fertilizer, and other agricultural chemical manufacturing|Benzoic acid, 3,6-dichloro-2-methoxy-, sodium salt (1:1): ACTIVE

The principal analytical method employed in the crop and milk residue analysis for dicamba is electron capture gas chromatography which is sensitive to 0.05 ppm (Smith, H., H. Suzuki, and M. Malina. (1965). Analysis of dicamba in crops and milk include a rapid cleanup method (J. Assoc. Off. Anal. Chem. (1965)) 48:1164). Improved residue analysis methodology is found in the Dicamba chapter of Vol. X, Specific Methods for Newer Pesticides, Analytical Methods of Pesticides and Plant Growth Regulators. 1977. Academic Press, Inc. New York. Additional methods of analysis for different substrates including water are available from Sandoz Crop Protection, 1300 E. Touhy Ave., Des Plaines, IL 60018. /Dicamba/|AOAC method No. 984.07. Dicamba, 2,4-D, and MCPP in Pesticide formulations. Combinations of dicamba, 2,4-D, and MCPP in liquid formulations as their salts are detected in any combination, using binary mobile phase 22% and 33% CH3CN-H2O, phosphate buffered, pH 2.68-2.7, on reverse phase bonded microparticulate column. /Salts of dicamba/|EAD Method 1618. Organo-halide Pesticides and PCB's, Organo-Phosphorus Pesticides, and Phenoxy-acid Herbicides by Wide Bore Capillary Column Gas Chromatography with Selective Detectors. Dicamba is measured using capillary gas chromatography with selected detectors. The detection limit is 110 ng/L.|EMSLC Method 515.1. Determination of Chlorinated Acids in Water by Gas Chromatography with an Electron Capture Detector. Dicamba is measured using capillary gas chromatography with an electron capture detector. The detection limit is 0.081 ug/L. /Dicamba/|For more Analytic Laboratory Methods (Complete) data for SODIUM 2-METHOXY-3,6-DICHLOROBENZOATE (6 total), please visit the HSDB record page.