2-(Methacryloyloxy)ethyl acetoacetate
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2-(Methacryloyloxy)ethyl acetoacetate
structure -
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CAS No:
21282-97-3
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Formula:
C10H14O5
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Chemical Name:
2-(Methacryloyloxy)ethyl acetoacetate
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Synonyms:
3-oxo-butanoicaci2-[(2-methyl-1-oxo-2-propenyl)oxy]ethylester;2-(Methacryloyloxy)ethyl acetoacetate,(2-Acetoacetoxy)ethyl methacrylate, AAEM, Ethylene glycol monoacetoacetate monomethacrylate, Lonzamon AAMEA PQ;2-(METHACRYLOYLOXY)E;Monomer AAEMA;ACETOACETIC ACID 2-(METHACRYLOYLOXY)ETHYL ESTER;ACETOACETOXY ETHYL 2-METHYLACRYLATE;ETHYL 2-((2-METHYL-1-OXO-2-PROPENYL)OXY)-3-OXO-BUTANOATE;ETHYLENE GLYCOL MONOACETOACETATE MONOMETHACRYLATE
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CAS No:
Description
Clear liquid.
Liquid
Clear liquid. Acetoacetoxyethyl Methacrylate [21282- 97-3], AAEM, has a pendant acetoacetoxyethyl group which can modify the physical properties of acrylic polymers by decreasing solution viscosity and lowering the glass transition temperature. In addition, the acetoacetyl group contains an active methylene group and a carbonyl group, which can be used to modify or cross-link the polymer [107].
2-(Methacryloyloxy)ethyl acetoacetate Basic Attributes
214.22
214.22
2099809
244-311-1
6L3EW3HZF2
TSCA listed
DTXSID7041388
Light yellow to Yellow to Orange
29189990
Characteristics
69.67000
1.62
yellowish Clear liquid.
1.122 g/mL at 25 °C (lit.)
<25 °C
100 °C/0.8 mmHg (lit.)
>230 °F
n20/D1.456
18.5g/L at 25℃
0.24Pa at 25℃
Non flammable
10.16±0.46(Predicted)
Storage temp. 2-8°C
Safety Information
UN 2810 6.1/PG 3
3
T,Xi
26-36/37-45-36
AK5600000
T,Xi
P280
36/37/38-43
UN 2810 6.1/PG 3
|Danger|H315 (20.51%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P272, P273, P280, P285, P302+P352, P304+P340, P304+P341, P305+P351+P338, P312, P321, P332+P313, P333+P313, P337+P313, P342+P311, P362, P363, P403+P233, P405, and P501|Aggregated GHS information provided by 543 companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, and P501|Aggregated GHS information provided by 38 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
2-(Methacryloyloxy)ethyl acetoacetate Use and Manufacturing
LONZAMON(R) AAEMA is a special methacrylic ester monomer with a reactive methylene group. It is suitable as comonomer for adhesives and coatings as well as copolymer for emulsion polymerisation.
Intermediates
Paints and coatings
2-(Methacryloyloxy)ethyl acetoacetate is a methylene active compound that may be used in the synthesis of 2-(methacryloyloxy)ethyl 6-methyl-2-oxo-4-phenyl-1,2,3,4- tetrahydropyrimidine-5-carboxylate. It may be used as a polymerizable chelating agent for metal alkoxides to form polymerizable oxide precursors.
1,000,000 - 10,000,000 lb
All other basic organic chemical manufacturing|Butanoic acid, 3-oxo-, 2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]ethyl ester: ACTIVE
Computed Properties
Molecular Weight:214.21
XLogP3:0.8
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:8
Exact Mass:214.08412354
Monoisotopic Mass:214.08412354
Topological Polar Surface Area:69.7
Heavy Atom Count:15
Complexity:280
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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2-(Methacryloyloxy)ethyl acetoacetate
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