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Home > Encyclopedia > GLYCEROL PROPOXYLATE-B-ETHOXYLATE

GLYCEROL PROPOXYLATE-B-ETHOXYLATE

GLYCEROL PROPOXYLATE-B-ETHOXYLATE structure

GLYCEROL PROPOXYLATE-B-ETHOXYLATE 

structure
  • CAS No:

    9082-00-2

  • Formula:

    C8H22O7

  • Chemical Name:

    GLYCEROL PROPOXYLATE-B-ETHOXYLATE

  • Synonyms:

    GLYCEROL PROPOXYLATE-B-ETHOXYLATE;1,2,3-Propanetriol,polymerwithmethyloxiraneandoxirane;Glycerol,ethyleneoxide,propyleneoxidepolymer;Glycerol,propyleneoxide,ethyleneoxidepolymer;Glycerolpoly(oxyethylene,oxypropylene)ether;Oxirane,methyl-,polymerwithoxirane,etherwith1,2,3-propanetriol(3:1);Glycerol polyethylene-propylene glycol ether;Glycerol propoxylate-block-ethoxylate average Mn ~4,000

  • Categories:

    Organic Chemistry  >  Cyanates

Description

93% Polyethylene-polypropylene glycol
generally occur as white, waxy, free-flowing prilled granules, or as cast solids. They are practically odorless and tasteless. At room temperature, poloxamer 124 occurs as a colorless liquid.


Liquid

GLYCEROL PROPOXYLATE-B-ETHOXYLATE Basic Attributes

194.23

102.068

208-750-2

TSCA listed

39072090

Characteristics

25.06

0.42170

Clear Colorless Liquid

1.02 g/mL at 25 °C

60-50°C

32.9°C at 760 mmHg

55.2°C

n20/D 1.466

H2O: <0.1% (w/w) at25°C

Prevent all contact with water and with moist atmosphere. Tanks must be clean, dry and rust-free. Prevent ingress of water. Must be stored in a diked (bunded) well- ventilated area, away from sunlight, ignition sources and other sources of heat. Nitrogen blanket recommended for large tanks (capacity 100 m3 or higher). Drums should be stacked to a maximum of 3 high. Maximum storage time: 6 months

<0.3 mm Hg ( 20 °C)

>1 (vs air)

LD50 oral in rabbit: 35gm/kg

Safety Information

2

R21; R23/24/25; R25; R36/37/38

S23; S24/25; S45; S36/37/39; S26

TQ8170000

T

P261, P271, P304+P312, P304+P340, P312

H332

Not Classified

GLYCEROL PROPOXYLATE-B-ETHOXYLATE Use and Manufacturing

Methods of Manufacturing

1. A process for the production of polyether polyols having an average hydroxyl functionality of at least 3 and a hydroxyl number of from 28 to 1000 by alkoxylating a mixture comprising: (a) from 20 to 80% by weight of sucrose (based on the sum of (a) and (b)), and (b) from 80 to 20% by weight of formitol having an average hydroxyl functionality of at least 3 (based on the sum of (a) and (b)). 2. The process of claim 1 wherein the mixture comprises: (a) from 40 to 75% by weight of sucrose (based on the sum of (a) and (b)), and (b) from 60 to 25% by weight of formitol (based on the sum of (a) and (b)). 3. The process of claim 1 wherein the formitol has an average hydroxyl functionality of from 3.3 to 5.7. 4. The process of claim 1 wherein the mixture further comprises 0.5 to 3% by weight water (based on the total quantity of sucrose and formitol). 5. The process of claim 1 wherein the mixture further comprises 2-20% by weight of a compound taken from the group consisting of a low molecular weight polyol, mono-amine, poly-amine and mixtures thereof (based on the total quantity of sucrose and formitol). 6. The process of claim 1 wherein the mixture has an average functionality with respect to alkylene oxides of from 4 to 7.

Uses

Polyethylene-polypropylene glycol
is a liquid surfactant polymer. Hard and soft surface cleaners, defoamers in coatings and water treatment. Lubricant in metal working, anti-foaming aid and extender for linear and cross-linked polyesters and polyurethanes. pyrethroid-based pesticide for use in mosquito control


Lubricants and lubricant additives


Lubricants and greases


Glycerol Propoxylate-block-ethoxylate is used in the production of polyurethane foams.

Production

25,000 - 100,000 lb

Mining (except oil and gas) and support activities|Oxirane, 2-methyl-, polymer with oxirane, ether with 1,2,3-propanetriol (3:1): ACTIVE|XU - indicates a substance exempt from reporting under the Chemical Data Reporting Rule, (40 CFR 711).

EPA Safer Chemical Functional Use Classes -> Defoamers|Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern

Computed Properties

Molecular Weight:230.26
Hydrogen Bond Donor Count:7
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:4
Exact Mass:230.13655304
Monoisotopic Mass:230.13655304
Topological Polar Surface Area:142
Heavy Atom Count:15
Complexity:52.1
Undefined Atom Stereocenter Count:1
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes

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