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Glycerol 1-monooleate

Glycerol 1-monooleate structure

CAS No:
111-03-5
Formula:
C21H40O4
Chemical Name:
Glycerol 1-monooleate
Synonyms:
9-Octadecenoic acid (9Z)-,2,3-dihydroxypropyl ester;Olein,1-mono-;9-Octadecenoic acid (Z)-,2,3-dihydroxypropyl ester;Glycerol 1-monooleate;α-Monoolein;1-Monoolein;1-Oleylglycerol;1-Oleoylglycerol;1-Monooleoylglycerol;Glycerin 1-monooleate;Glycerol α-cis-9-octadecenate;Glycerol α-monooleate;1-Glyceryl oleate;Glyceryl monooleate;Glycerol 1-oleate;rac-1-Monooleoylglycerol;rac-1-Monoolein;1-Monooleoyl-rac-glycerol;Danisco MO 90;2,3-Dihydroxypropyl oleate;1-Mono(cis-9-octacenoyl)glycerol;Rylo MG 19;α-Glyceryl monooloeate;1-Oleoyl-rac-glycerol;Nofable GO 991;Glycerol 1-(9Z-octadecenoate);1-Monooleoyl-rac-glycerol;GO 991;925-14-4;30836-40-9;33978-07-3
Categories:
Cosmetic Ingredient > Perfuming

Description

White Waxy SolidChEBI: A 1-monoglyceride where the acyl group is oleoyl.

DryPowder; Liquid; OtherSolid|OtherSolid|Liquid|pale yellow viscous oily liquid with a faint fatty odour

1-oleoylglycerol is a 1-monoglyceride where the acyl group is oleoyl. It has a role as a plant metabolite. It is a 1-acylglycerol 18:1 and a monooleoylglycerol. It derives from an oleic acid.

Glycerol 1-monooleate Basic Attributes

Molecular Weight：

356.54000

Exact Mass：

356.54

EC Number：

266-951-0

NSC Number：

406285

DSSTox ID：

DTXSID3027875|DTXSID6028319|DTXSID3029360|DTXSID3042003

Color/Form：

PLATES FROM ETHANOL|YELLOW OIL OR SOFT SOLID

HScode：

29161500

Characteristics

PSA：

66.76000

XLogP3：

4.92030

Density：

0.9407 g/cm³ @ Temp: 35 °C

Melting Point：

35 °C

Boiling Point：

238-240 °C @ Press: 3-4 Torr

Flash Point：

155.4ºC

Refractive Index：

1.483

Water Solubility：

chloroform: 50 mg/mL, clear, colorless ;INSOL IN WATER; SOL IN ETHANOL, ETHER, CHLOROFORM

Storage Conditions：

-20ºC

Odor：

SWEET

Taste：

FATTY TASTE

Collision Cross Section：

202.8 Å² [M+H]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|197.3 Å² [M+Na]+ [CCS Type: DT, Method: single field calibrated with ESI Low Concentration Tuning Mix (Agilent)]|202.9 Å² [M+H]+

Experimental Properties：

IODINE VALUE 65-80

Safety Information

Transport codes：

UN 1282 3/PG 2

wgk germany：

hazard class code：

R11

safety instructions：

S36-S37

Marks：

F; Xn

Stability/Shelf Life：

Hygroscopic

Precautionary statement(s)：

P264, P270, P280, P301+P312, P305+P351+P338, P330, P337+P313, P501

Hazard Statements：

H302

FDA Requirements：

SYNTHETIC FLAVOR INGREDIENTS- GLYCERYL MONOOLEATE: REGULATION 172.515.|REGULATION FDA 121.1164; LIMITATIONS: SYNTHETIC FLAVOR.

GHS Classification：

Not Classified

Drug Information

Human Toxicity Excerpts：

TREATMENT OF HUMAN ERYTHROCYTE GHOST MEMBRANES WITH THE FUSOGENIC LIPID GLYCEROL MONOOLEATE INCREASED THE FLUIDITY OF THE MEMBRANE LIPIDS, BUT THE NONFUSOGENIC LIPID GLYCEROL MONOSTEARATE HAD NO EFFECT.|IF ANY OF THESE ESTERS IS SIGNIFICANTLY TOXIC, THE ACID PORTION MUST BE HELD RESPONSIBLE, NOT THE GLYCEROL. /GLYCEROL ESTERS/

MeSH Entry Terms：

1-oleoyl monoglyceride

Glycerol 1-monooleate Use and Manufacturing

Methods of Manufacturing

REACTION OF OLEIC ACID WITH GLYCEROL, PRODUCING A MIXTURE (PREDOMINANTLY MONOOLEATE)|SEE MONOGLYCERIDE. PRODUCED SYNTHETICALLY BY ALCOHOLYSIS OF FATS WITH GLYCEROL, YIELDING A MIXTURE OF MONO-, DI-, & TRIGLYCERIDES WHICH IS PREDOMINANTLY MONOGLYCERIDES. /MONOGLYCERIDE/

Uses

Monoglycerides fatty acid esters 93% 1-Oleoyl, 7% 2-oleoyl. glyceryl oleate is an emollient and stabilizer derived from olive oil. It is a water-in-oil emulsifier that allows for softer emulsions than glyceryl stearate. Glyceryl Monooleate is a flavoring agent that is prepared by esterification of commercial oleic acid that is derived either from edible sources or from tall oil fatty acids. It contains and glyceryl esters of fatty acids present in commercial oleic acid. The ingredient is also used as an adjuvant and as a solvent and vehicle.

Fuels and fuel additives|Lubricants and lubricant additives|Surface active agents

Cleaning and furnishing care products|Plastic and rubber products not covered elsewhere

Production

1,000,000 - 10,000,000 lb|100,000 - 500,000 lb|(1972) 1.25X10+9 GRAMS|(1975) 1.71X10+9 GRAMS

Formulations：

GRADES: EDIBLE; TECHNICAL.

Manufacturing Info：

All other chemical product and preparation manufacturing|9-Octadecenoic acid (9Z)-, monoester with 1,2,3-propanetriol: ACTIVE|Plastics product manufacturing|Glycerides, C14-18 and C16-18-unsatd. mono- and di-: ACTIVE|Utilities|9-Octadecenoic acid (9Z)-, 2,3-dihydroxypropyl ester: ACTIVE|FEMA NUMBER 2526

Use Classification：

EPA Safer Chemical Functional Use Classes -> Surfactants|Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern|Flavoring Agents -> JECFA Flavorings Index|Lipids -> Glycerolipids [GL] -> Monoradylglycerols [GL01] -> Monoacylglycerols [GL0101]|Cosmetics -> Emollient; Emulsifying

Food Additive Classes：

Flavoring Agents

Computed Properties

Molecular Weight:356.5
XLogP3:6.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:19
Exact Mass:356.29265975
Monoisotopic Mass:356.29265975
Topological Polar Surface Area:66.8
Heavy Atom Count:25
Complexity:315
Undefined Atom Stereocenter Count:1
Defined Bond Stereocenter Count:1
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

Material

Methyl oleate

Glycerol

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Guide of Glycerol 1-monooleate

Description
Basic Attributes
Characteristics
Safety Information
Drug Information
Use and Manufacturing
Computed Properties
Material
Recommended Suppliers
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Glycerol 1-monooleate

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