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Home > Encyclopedia > (1S,1′S)-1,1′-(1,2-Ethanediyl)bis[1-(2-methoxyphenyl)-1-phenylphosphine]

(1S,1′S)-1,1′-(1,2-Ethanediyl)bis[1-(2-methoxyphenyl)-1-phenylphosphine]

(1S,1′S)-1,1′-(1,2-Ethanediyl)bis[1-(2-methoxyphenyl)-1-phenylphosphine] structure

(1S,1′S)-1,1′-(1,2-Ethanediyl)bis[1-(2-methoxyphenyl)-1-phenylphosphine] 

structure
  • CAS No:

    97858-62-3

  • Formula:

    C28H28O2P2

  • Chemical Name:

    (1S,1′S)-1,1′-(1,2-Ethanediyl)bis[1-(2-methoxyphenyl)-1-phenylphosphine]

  • Synonyms:

    Phosphine,1,1′-(1,2-ethanediyl)bis[1-(2-methoxyphenyl)-1-phenyl-,(1S,1′S)-;Phosphine,1,2-ethanediylbis[(2-methoxyphenyl)phenyl-,[S-(R*,R*)]-;Phosphine,1,2-ethanediylbis[(2-methoxyphenyl)phenyl-,(1S,1′S)-;(1S,1′S)-1,1′-(1,2-Ethanediyl)bis[1-(2-methoxyphenyl)-1-phenylphosphine];(S,S)-DIPAMP;(S,S)-DIPAMP

  • Categories:

    Catalyst and Auxiliary  >  Polymer

(1S,1′S)-1,1′-(1,2-Ethanediyl)bis[1-(2-methoxyphenyl)-1-phenylphosphine] Basic Attributes

458.47

458.47

214-152-2

HS6F5EW3U6

Characteristics

102-103 °C

580.2±45.0 °C(Predicted)

85 ° (C=1, CHCl3)

Safety Information

3

36/37/38

26-36/37

Xi

|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P264, P280, P302+P352, P305+P351+P338, P321, P332+P313, P337+P313, and P362|The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

(1S,1′S)-1,1′-(1,2-Ethanediyl)bis[1-(2-methoxyphenyl)-1-phenylphosphine] Use and Manufacturing

Rhodium DIPAMP catalysts have shown high activity and enantioselectivity in the asymmetric hydrogenation of enamides, enol acetates and olefins.

Computed Properties

Molecular Weight:458.5
XLogP3:5.8
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:9
Exact Mass:458.15645413
Monoisotopic Mass:458.15645413
Topological Polar Surface Area:18.5
Heavy Atom Count:32
Complexity:472
Defined Atom Stereocenter Count:2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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