Titanium tetrachloride
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Titanium tetrachloride
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CAS No:
7550-45-0
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Formula:
Cl4Ti
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Chemical Name:
Titanium tetrachloride
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Synonyms:
Titanium chloride (TiCl4) (T-4)-;Titanium chloride (TiCl4);Titanium tetrachloride;Tetrachlorotitanium;Titanium chloride;Titanium(IV) chloride;TC 36;8011-53-8;15612-71-2;44246-22-2
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CAS No:
Description
Description: Titanium tetrachloride is a noncombustible, colorless to light yellow liquid that fumes in air. Penetrating acrid odor. Colorless liquid. Fumes strongly when exposed to moist air, forming a dense and persistent white cloud. Soluble in dilute hydrochloric acid; soluble in water with evolution of heat; concentrated aqueous solutions are stable and corrosive; dilute solutions precipitate insoluble basic chlorides.
Characteristics
0
2.75800
Light yellow to dark brown Solution
1.726 g/cm3
-24.1 °C
136.4 °C
46 °F
1.61
Solubility in water: reaction
Flammables area
50 mm Hg ( 55 °C)
Relative vapour density (air = 1): 6.5
Inhalation-rat LC50: 400 mg/m3/2 hours; inhalation-mouse LC50: 100 mg/m3/2 hours
Heat and smoke in the presence of water, producing toxic hydrogen chloride gas; high heat decomposition of toxic chloride and titanium-containing fumes
Safety Information
II
8
UN 3289 6.1/PG 2
2
36/37/38-67-65-63-48/20-34-14-11-23-40-37-48/23-39/23-20/21/22-36/38
26-7/8-62-46-45-36/37/39-24/25-23-16-60
XR1925000
C,F,Xi,T
The warehouse is ventilated, low temperature and dry; stored separately from alkalis, oxidants, organic matter and flammable substances
Stable. Reacts with water. Incompatible with moisture, ammonia, amines, alcohols, potassium and other chemically active metals.
P260-P280-P284-P305 + P351 + P338-P310
H314-H330-H370-H372
Titanium tetrachloride Use and Manufacturing
In the chlorination method, the high-titanium slag and petroleum coke are proportioned, crushed, and reacted with chlorine gas to generate titanium tetrachloride gas. After condensation, a liquefied titanium tetrachloride liquid is obtained, which is filtered and distilled to obtain tetrachloride. Titanium products. Its TiO2+2C+2C12→TiCl4+2CO↑TiO2+C+2C12→TiCl4+CO2↑
manufacture of titanium compounds, iridescent glass and artificial pearls.Formerly used with potassium bitartrate as a mordant in textile industry, and with dyewoods in dyeing leather; also as smoke-producing screen with ammonia.
Computed Properties
Molecular Weight:189.7
Hydrogen Bond Acceptor Count:4
Exact Mass:189.820401
Monoisotopic Mass:187.823351
Heavy Atom Count:5
Covalently-Bonded Unit Count:5
Compound Is Canonicalized:Yes
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