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Potassium methoxide

Potassium methoxide structure

Potassium methoxide 

structure
  • CAS No:

    865-33-8

  • Formula:

    CH4O.K

  • Chemical Name:

    Potassium methoxide

  • Synonyms:

    Methanol,potassium salt (1:1);Methanol,potassium salt;Potassium methoxide;Potassium methylate;Feldalat KM;Methoxypotassium;Potassium methanolate

  • Categories:

    Organic Chemistry  >  Organometallic Compounds

Description

solid


Liquid|WHITE-TO-YELLOW HYGROSCOPIC POWDER.

Potassium methoxide Basic Attributes

70.13

69.982094

212-736-1

45MYQ0GWGB

1731

3206

DTXSID1029627

29051900

Characteristics

23.1

-0.74

Clear colorless Liquid

0.950 g/cm3

-20°C

84°C

7°C

n20/D 1.37

H2O: may decompose;soluble in methanol and ethanol.

Flammables area

Vapour pressure, Pa at 25°C: (negligible)

>50 °C

Safety Information

II

4.2

UN 3274 3/PG 2

1

11-14-34-67-65-63-48/20-39/23/24/25-38-23/24/25

8-16-26-43-45-62-46-36/37/39-33-29-25

F,T,C

Fireproof. Separated from strong oxidants, acids, metals and food and feedstuffs. Dry. Cool. Well closed. Store in an area having corrosion resistant concrete floor. Store in an area without drain or sewer access.

Stable. Reacts violently with water. Moisture sensitive. Absorbs carbon dioxide from the air. Incompatible with acids, strong oxidizing agents, acid chlorides, acid anhydrides, alkali metals.

P235 + P410-P280-P305 + P351 + P338-P310

H251-H314

Highly flammable. Many reactions may cause fire or explosion. Risk of fire and explosion on contact with water, moisture or metals.

|Danger|H228 (46.91%): Flammable solid [Danger Flammable solids]|P210, P234, P235+P410, P240, P241, P260, P264, P270, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P370+P378, P390, P404, P405, P407, P413, P420, and P501|Aggregated GHS information provided by 195 companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H251: Self-heating; may catch fire [Danger Self-heating substances and mixtures]|P235+P410, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P407, P413, P420, and P501

NO water. NO hydrous agents. Use dry powder, dry sand. In case of fire: keep cylinder cool by spraying with water. NO direct contact of the substance with water.

Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Sweep spilled substance into covered dry plastic containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT wash away into sewer.

Fireproof. Separated from strong oxidants, acids, metals and food and feedstuffs. Dry. Cool. Well closed. Store in an area having corrosion resistant concrete floor. Store in an area without drain or sewer access.

A harmful concentration of airborne particles can be reached quickly when dispersed.

The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation may cause lung oedema, but only after initial corrosive effects on eyes and/or airways have become manifest.

NO open flames, NO sparks and NO smoking. NO contact with water.

AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!

Use local exhaust and breathing protection.

Protective gloves. Protective clothing.

Wear face shield or eye protection in combination with breathing protection.

Drug Information

Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention.


First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer immediately for medical attention.


Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention.

potassium methylate

Serious local effects by all routes of exposure.

Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing.


Redness. Pain. Serious skin burns.


Redness. Pain. Blurred vision. Severe deep burns.

Potassium methoxide Use and Manufacturing

Uses

Used as a condensing agent, a catalyst for producing methyl formate, a strong alkaline catalyst for dimethylformamide, and also as a raw material for medicine


Fuels and fuel additives

Methanol, potassium salt (1:1): ACTIVE

Computed Properties

Molecular Weight:70.132
Hydrogen Bond Acceptor Count:1
Exact Mass:69.98209620
Monoisotopic Mass:69.98209620
Topological Polar Surface Area:23.1
Heavy Atom Count:3
Complexity:4.8
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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