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Chlorocyclohexylmagnesium

Chlorocyclohexylmagnesium structure

Chlorocyclohexylmagnesium 

structure
  • CAS No:

    931-51-1

  • Formula:

    C6H11ClMg

  • Chemical Name:

    Chlorocyclohexylmagnesium

  • Synonyms:

    Magnesium,chlorocyclohexyl-;Chlorocyclohexylmagnesium;Cyclohexylmagnesium chloride

  • Categories:

    Organic Chemistry  >  Organometallic Compounds

Description

clear very dark brown solution

Chlorocyclohexylmagnesium Basic Attributes

142.91

142.04000

213-237-1

DTXSID2061309

29319090

Characteristics

0

2.97780

Clear very dark brown Solution

0.871 g/mL at 25ºC

80.7ºC at 760 mmHg

−40 °F

It reacts violently with water.

Flammables + water-Freezer (-20°C)e area

Moisture sensitive|... May react violently with water. /Methyl magnesium bromide in ethyl ether/

Safety Information

4.2

UN 3399 4.3/PG 1

1

12-14/15-19-22-34-67-66-14-65-48/20-40-37-11-63

7-9-16-26-29-33-36/37/39-43-45-62

F+,C,F

P210-P280-P305 + P351 + P338-P310

H225-H314

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

|Danger|H225 (43.06%): Highly Flammable liquid and vapor [Danger Flammable liquids]|P210, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P370+P378, P403+P235, P405, and P501|Aggregated GHS information provided by 72 companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

/GUIDE 138: SUBSTANCES - WATER-REACTIVE (EMITTING FLAMMABLE GASES)/ Fire or Explosion: Produce flammable gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard. /Organometallic substance, liquid, water-reactive, flammable/|/GUIDE 138: SUBSTANCES - WATER-REACTIVE (EMITTING FLAMMABLE GASES)/ Health: Inhalation or contact with vapors, substance, or decomposition products may cause severe injury or death. May produce corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution. /Organometallic substance, liquid, water-reactive, flammable/|/GUIDE 138: SUBSTANCES - WATER-REACTIVE (EMITTING FLAMMABLE GASES)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meter (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate the area before entry. /Organometallic substance, liquid, water-reactive, flammable/|/GUIDE 138: SUBSTANCES - WATER-REACTIVE (EMITTING FLAMMABLE GASES)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing will only provide limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. /Organometallic substance, liquid, water-reactive, flammable/|For more DOT Emergency Guidelines (Complete) data for CYCLOHEXYLMAGNESIUM CHLORIDE (8 total), please visit the HSDB record page.

Chlorocyclohexylmagnesium Use and Manufacturing

Methods of Manufacturing

REACTION OF CYCLOHEXYL CHLORIDE WITH MAGNESIUM IN ANHYDROUS DIETHYL ETHER, USUALLY IN THE PRESENCE OF AN INITIATOR

Uses

CHEM INT, EG, FOR CYCLOHEXYLSILANE

Magnesium, chlorocyclohexyl-: ACTIVE

Computed Properties

Molecular Weight:142.91
Hydrogen Bond Acceptor Count:2
Exact Mass:142.0399697
Monoisotopic Mass:142.0399697
Heavy Atom Count:8
Complexity:35.5
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes

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