Resin acids, calcium salts

642.96400

642.39600

236-677-6

1313|1314

DTXSID7093820

YELLOWISH WHITE AMORPHOUS POWDER OR LUMPS|Amber; very dark brown

3806201000

80.26000

7.74300

Calcium resinate is a grayish white to yellow amorphous powder which can be fused into grayish lumps. If it comes in contact with air, spontaneous heating may result. This heat may be sufficient to ignite the material itself or surrounding combustible material. It is insoluble in water.

1.13 at 25 deg C (solid)

439.5ºC at 760 mmHg

208.1ºC

SOL IN ACID, AMYL ACETATE, BUTYL ACETATE, ETHER, AMYL ALC; INSOL IN WATER

/STORE IN COOL/...PLACES...PROVIDE ADEQUATE VENTILATION IN STORAGE SPACE...LOCATE STORAGE AREA...AWAY FROM AREAS OF FIRE HAZARD... REDUCING OR EASILY OXIDIZED MATERIALS MUST BE KEPT APART FROM...OXIDIZING AGENTS...OR MATERIALS WHICH...EVOLVE HEAT.

ROSIN

Highly flammable. The powder spontaneously heats in the presence of air and moisture. This heat may be sufficient to ignite surrounding combustible materials. The solid is insoluble in water.

Reducing Agents, Strong

Highly Flammable

Inorganic reducing agents, such as CALCIUM RESINATE, react with oxidizing agents to generate heat and products that may be flammable, combustible, or otherwise reactive. Their reactions with oxidizing agents may be violent.

480 °F (USCG, 1999)

III

4.1

UN 1313

P261, P272, P280, P302+P352, P321, P333+P313, P363, P501

H317

Excerpt from ERG Guide 133 [Flammable Solids]: Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare-burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished. (ERG, 2016)|Flammable - 3rd degree, Reactive - 1st degree

Not Classified| |Warning|H317: May cause an allergic skin reaction [Warning Sensitization, Skin]|P261, P272, P280, P302+P352, P321, P333+P313, P363, and P501

Excerpt from ERG Guide 133 [Flammable Solids]: SMALL FIRE: Dry chemical, CO2, sand, earth, water spray or regular foam. LARGE FIRE: Water spray, fog or regular foam. Move containers from fire area if you can do it without risk. Fire Involving Metal Pigments or Pastes (e.g. "Aluminum Paste") Aluminum Paste fires should be treated as a combustible metal fire. Use DRY sand, graphite powder, dry sodium chloride-based extinguishers, G-1® or Met-L-X® powder. Also, see ERG Guide 170. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Cool containers with flooding quantities of water until well after fire is out. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)

Excerpt from ERG Guide 133 [Flammable Solids]: As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet). FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 133 [Flammable Solids]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Do not touch or walk through spilled material. SMALL DRY SPILL: With clean shovel, place material into clean, dry container and cover loosely; move containers from spill area. LARGE SPILL: Wet down with water and dike for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2016)

Dust mask; goggles or face shield; gloves (USCG, 1999)|Dust mask, goggles or face shield; gloves

MODERATE WHEN HEATED; CAN REACT WITH OXIDIZING MATERIALS.|FLAMMABLE; DANGEROUS FIRE RISK; SPONTANEOUS HEATING.

/GUIDE 133: FLAMMABLE SOLIDS/ Fire or Explosion: Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished. /Calcium resinate; Calcium resinate, fused/|/GUIDE 133: FLAMMABLE SOLIDS/ Health: Fire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution. /Calcium resinate; Calcium resinate, fused/|/GUIDE 133: FLAMMABLE SOLIDS/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. /Calcium resinate; Calcium resinate, fused/|/GUIDE 133: FLAMMABLE SOLIDS/ Protection Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. /Calcium resinate; Calcium resinate, fused/|For more DOT Emergency Guidelines (Complete) data for CALCIUM RESINATE (8 total), please visit the HSDB record page.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./|The International Air Transport Association (IATA) Dangerous Goods Regulations are published by the IATA Dangerous Goods Board pursuant to IATA Resolutions 618 and 619 and constitute a manual of industry carrier regulations to be followed by all IATA Member airlines when transporting hazardous materials.|The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.

Inhalation of fumes from heated chemical may cause irritation of nose... Contact with eyes causes irritation. Contact of molten material with skin causes burns.

Inhalation of fumes from heated chemical may cause irritation of nose and throat. Ingestion causes irritation of nose and throat. Contact with eyes causes irritation. Contact of molten material with skin causes burns. (USCG, 1999)

INHALATION: move victim to fresh air; get medical help immediately. INGESTION: give large amounts of water; induce vomiting. EYES: flush immediately with cold water; get medical help immediately. SKIN: if molten chemical burns skin, apply cold water immediately; get medical help for burn treatment. (USCG, 1999)

GRADES: TECHNICAL; FUSED.

Paint and coating manufacturing|Calcium resinate: ACTIVE

Fire Hazards -> Flammable - 3rd degree, Reactive - 1st degree