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Home > Encyclopedia > 1-Chlorododecane

1-Chlorododecane

1-Chlorododecane structure

1-Chlorododecane 

structure
  • CAS No:

    112-52-7

  • Formula:

    C12H25Cl

  • Chemical Name:

    1-Chlorododecane

  • Synonyms:

    Dodecane,1-chloro-;1-Chlorododecane;Lauryl chloride;Dodecyl chloride;n-Dodecyl chloride;1-Dodecyl chloride;n-Lauryl chloride;NSC 57107

  • Categories:

    Organic Chemistry  >  Free Radicals

Description

LiquidClear colorless oily liquid.


Lauryl chloride is a clear colorless oily liquid. (NTP, 1992)|Liquid


Lauryl chloride is a clear colorless oily liquid. (NTP, 1992)

1-Chlorododecane Basic Attributes

204.78

204.78

203-981-5

WE8O8J0UTK

57107

3265

DTXSID0025492

29189090

Characteristics

0

6.9

Clear colorless Liquid

0.8673 g/cm3 @ Temp: 22 °C

-9.3 °C

260 °C

130 °C

n 20/D 1.443

H2O: 0.0068 g/L (20 ºC)

Store below +30°C.

116 mm Hg at 41.9° F ; 137 mm Hg at 59.2° F; 143.9 mm Hg at 68.2° F (NTP, 1992)

Insoluble in water.

Halogenated Organic Compounds

LAURYL CHLORIDE may be incompatible with strong oxidizing and reducing agents. May be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Safety Information

III

9

UN 3082 9/PG 3

3

40-50/53-38-66

24-36/37-60-61-37-46

Xn,N,Xi

P280

H351-H410

This chemical is combustible. (NTP, 1992)

|Warning|H315 (22%): Causes skin irritation [Warning Skin corrosion/irritation]|P201, P202, P264, P273, P280, P281, P302+P352, P308+P313, P321, P332+P313, P362, P391, P405, and P501|Aggregated GHS information provided by 50 companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this material in a refrigerator. STORE AWAY FROM SOURCES OF IGNITION. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. (ERG, 2016)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

1-Chlorododecane Use and Manufacturing

Methods of Manufacturing

It is obtained by chlorination of dodecanol through thionyl chloride.

Uses

Barchlor(R) 12S is used as a chemical intermediate.


Intermediates

Production

100,000 - 500,000 lb

All other basic organic chemical manufacturing|Dodecane, 1-chloro-: ACTIVE

Computed Properties

Molecular Weight:204.78
XLogP3:6.9
Rotatable Bond Count:10
Exact Mass:204.1644785
Monoisotopic Mass:204.1644785
Heavy Atom Count:13
Complexity:81.2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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