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Silver trifluoroacetate

Silver trifluoroacetate structure

Silver trifluoroacetate 

structure
  • CAS No:

    2966-50-9

  • Formula:

    C2HF3O2.Ag

  • Chemical Name:

    Silver trifluoroacetate

  • Synonyms:

    Acetic acid,2,2,2-trifluoro-,silver(1+) salt (1:1);Acetic acid,trifluoro-,silver(1+) salt;Silver mono(trifluoroacetate);Silver(1+) trifluoroacetate;Silver trifluoroacetate;Trifluoroacetic acid silver(1+) salt;Silver(I) trifluoroacetate;Silver perfluoroacetate;Trifluorooacetic acid,silver salt (1:1);Silver(1+) 2,2,2-trifluoroacetate;380240-19-7;1964452-54-7;2446500-25-8

  • Categories:

    Catalyst and Auxiliary  >  Precious Metal Catalysts

Description

light beige to grey crystalline powder

Silver trifluoroacetate Basic Attributes

220.88

219.890137

221-004-0

DTXSID7062748

28432900

Characteristics

40.1

-0.70140

White to grey crystalline powder

251-253 °C (decomp)

72.2°C at 760 mmHg

SOLUBLE

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked. Store protected from moisture. Store protected from light.

96.2 mmHg at 25°C

Safety Information

I; II; III

NONH for all modes of transport

3

R36/37/38;R50

S26-S61-S36/39

Xi:Irritant;N:Dangerousfortheenvironment;

Stable under normal temperatures and pressures. Light sensitive. Hygroscopic: absorbs moisture or water from the air.

P305 + P351 + P338

H315-H319

|Danger|H300 (86.36%): Fatal if swallowed [Danger Acute toxicity, oral]|P261, P264, P270, P271, P273, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P391, P403+P233, P405, and P501|Aggregated GHS information provided by 44 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Silver trifluoroacetate Use and Manufacturing

Methods of Manufacturing

2.5 g (0, 0147 M) AgNO3was dissolved in20 cm3 of water in a 100 ml flask, then solution of1.715 g (0, 0162 M) sodium carbonate in 30 cm3 ofwater was added drop wise slowly at room temperature to the AgNO3 solution, stirred for 30minutes, the precipitate was filtered off, washed withwater and dried in a vacuum-desiccator.Trifluoroacetic acid was poured to the residue andthe solution was stirred with a magnetic stirrer, rotary evaporated and dried under vacuum. Theyield is 2.3 g of silver trifluoroacetate. Found: C-10, 859 percent, Obtained: C-11, 105 percent.3.4 g of sodium trifluoroacetate was dissolved in 6 g of water to prepare an aqueous solution. An aqueous solution prepared by dissolving 3.39 g of silver nitrate in 3 g of water was added thereto at room temperature. The resulting aqueous solution was extracted 10 times with 5 ml of diethyl ether and the combined extracts were dried over anhydrous magnesium sulfate. The magnesium sulfate was filtered off and the ether solution was concentrated on a rotary evaporator to precipitate a white solid. Further, the mixture was dried by heating on a rotary evaporator under reduced pressure at 50 ° C. for 2 hours to obtain 1.5 g of a white powder of silver trifluoroacetate.

Acetic acid, 2,2,2-trifluoro-, silver(1+) salt (1:1): ACTIVE

Computed Properties

Molecular Weight:220.88
Hydrogen Bond Acceptor Count:5
Exact Mass:219.89013
Monoisotopic Mass:219.89013
Topological Polar Surface Area:40.1
Heavy Atom Count:8
Complexity:77.9
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes

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