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Home > Encyclopedia > Perfluorodecanoic acid

Perfluorodecanoic acid

Perfluorodecanoic acid structure

Perfluorodecanoic acid 

structure
  • CAS No:

    335-76-2

  • Formula:

    C10HF19O2

  • Chemical Name:

    Perfluorodecanoic acid

  • Synonyms:

    Decanoic acid,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluoro-;Decanoic acid,nonadecafluoro-;2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Nonadecafluorodecanoic acid;Perfluorodecanoic acid;Nonadecafluorodecanoic acid;Perfluoro-n-decanoic acid;Nonadecafluoro-n-decanoic acid;Perfluorocapric acid;Perfluoro-1-nonanecarboxylic acid;PFDA

  • Categories:

    Organic Chemistry  >  Carboxylic Acids and Derivatives

Description

white crystalline powder


Perfluorodecanoic acid is a liquid. (NTP, 1992)


Perfluorodecanoic acid is a liquid. (NTP, 1992)|Perfluorodecanoic acid is a fluoroalkanoic acid that is perfluorinated decanoic acid. It has a role as a xenobiotic and an environmental contaminant. It derives from a decanoic acid.

Perfluorodecanoic acid Basic Attributes

514.08

514.08

1810811

206-400-3

2811

DTXSID3031860

2915900090

Characteristics

37.30000

9.53

Perfluorodecanoic acid is a liquid. (NTP, 1992)

1.8±0.1 g/cm3

67-72 °C

144-170 °C @ Press: 130-158 Torr

218°C

1.289

methanol: soluble 10%, clear to very slightly hazy, colorless to faintly yellow

2-8°C

~10 mm Hg ( 0 °C)

LD50 orl-rat: 57 mg/kg TXAPA9 85,169,86

174.29 Ų [M-H]-

No rapid reaction with air. No rapid reaction with water.

Acids, Carboxylic

PERFLUORODECANOIC ACID is incompatible with strong oxidizing agents. (NTP, 1992)

Safety Information

III

6.1

UN 2811 6.1/PG 2

3

25-36/37/38

26-45

HD9900000

T,C

Corrosive

Stable. Incompatible with strong bases, oxidizing agents, reducing agents.

P261-P301 + P310-P305 + P351 + P338

H301-H315-H319-H335

Flash point data on this compound are not available. It is probably combustible. (NTP, 1992)

|Danger|H351: Suspected of causing cancer [Warning Carcinogenicity]|P201, P202, P260, P263, P264, P270, P281, P308+P313, P405, and P501

Fires involving this material can be controlled with a dry chemical, carbon dioxide, or Halon extinguisher. (NTP, 1992)

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. then use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. STORAGE PRECAUTIONS: You should store this chemical under ambient temperatures, and keep it away from oxidizing materials. (NTP, 1992)

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Drug Information

ACUTE/CHRONIC HAZARDS: Decomposition products of this compound include carbon monoxide, carbon dioxide, and hydrogen fluoride. It may be harmful by inhalation, ingestion, or skin absorption. (NTP, 1992)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment. INHALATION: IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used; if not available, use a level of protection greater than or equal to that advised under Protective Clothing. INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992)

nonadecafluoro-n-decanoic acid

Perfluorodecanoic acid Use and Manufacturing

Decanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluoro-: ACTIVE|S - indicates a substance that is identified in a final Significant New Use Rule.

PFAS (per- and polyfluoroalkyl substances) -> OECD Category|PFAS

Computed Properties

Molecular Weight:514.08
XLogP3:6.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:21
Rotatable Bond Count:8
Exact Mass:513.9673143
Monoisotopic Mass:513.9673143
Topological Polar Surface Area:37.3
Heavy Atom Count:31
Complexity:701
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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