(4-FLUOROBENZYL)TRIPHENYLPHOSPHONIUMCHLORIDE
-
(4-FLUOROBENZYL)TRIPHENYLPHOSPHONIUMCHLORIDE
structure -
-
CAS No:
3462-95-1
-
Formula:
C25H21ClFP
-
Chemical Name:
(4-FLUOROBENZYL)TRIPHENYLPHOSPHONIUMCHLORIDE
-
Synonyms:
(4-Fluorobenzyl)triphenylphosphonium chloride;(4-fluorophenylmethyl)triphenylphosphonium chloride;Phosphonium, [(4-fluorophenyl)methyl]triphenyl-, chloride;ACMC-20a9k1;C25H21ClFP;KSC495G9T;SCHEMBL376693;CTK3J5399;KS-00000IKS;DTXSID80369940
- Categories:
-
CAS No:
(4-FLUOROBENZYL)TRIPHENYLPHOSPHONIUMCHLORIDE Basic Attributes
406.86
406.105347
4075331
DTXSID80369940
2931900090
Safety Information
36/37/38
37/39-26
Xi
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
H315
|Warning|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 43 companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
(4-FLUOROBENZYL)TRIPHENYLPHOSPHONIUMCHLORIDE Use and Manufacturing
General procedure: The synthesis of trans-3a is used as an example: a mixture of 4.0g (2.78mmol) of 4-fluorobenzyl chloride and 8.73g (3.30mmol) triphenylphosphine in 12mL of benzene was refluxed for 2 days to yield white solid. Collect the solid by suction filtration and (4-fluorobenzyl)-triphenylphosphonium salt was obtained in 82percent yield. Afterward, a mixture of 9.97g (2.5mmol) of the previous salt, 2.37g (2.2mmol) of benzaldehyde, and 0.82g (3.11mmol) of 18-crown-6 in 56mL of dichloromethane was stirred violently and 27mL of 50percent aqueous solution of KGeneral procedure: To a solution of substituted benzyl halide in toluene was added triphenylphosphine (1.5 eq) and the mixture was refluxed. After cooling, the precipitate was filtered to give the target compound.
Computed Properties
Molecular Weight:406.9
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:406.1053435
Monoisotopic Mass:406.1053435
Heavy Atom Count:28
Complexity:378
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes
Learn More Other Chemicals
-
APO-10
2190-95-6
-
Indium phosphide
22398-80-7
-
Dimethylvinphos
2274-67-1
-
(4-Methoxybenzyl)triphenylphosphonium chloride Formula
3462-97-3
-
(3-chloro-2-oxopropyl) dihydrogen phosphate Formula
23743-97-7
-
Piperophos Formula
24151-93-7
-
(2-bromo-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonic acid,hydrate Structure
209736-59-4
-
Dibutyl phenyl phosphate Structure
2528-36-1
-
What is P-(1Z)-1-Propen-1-ylphosphonic acid
25383-06-6
-
What is CGS35066
261619-50-5
- Hot Searches
- barium hydroxide
- propyne
- n2o4 lewis structure
- 9 me bc
- nitrate formula
- pbso4
(4-FLUOROBENZYL)TRIPHENYLPHOSPHONIUMCHLORIDE
SDSRequest for Quotation