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Palladium diacetate

Palladium diacetate structure

Palladium diacetate 

structure
  • CAS No:

    3375-31-3

  • Formula:

    C2H4O2.1/2Pd

  • Chemical Name:

    Palladium diacetate

  • Synonyms:

    Acetic acid,palladium(2+) salt (2:1);Acetic acid,palladium(2+) salt;Palladium acetate (Pd(OAc)2);Palladium diacetate;Palladium(2+) acetate;Palladous acetate;Palladium(II) acetate;Palladium acetate (Pd(OCOCH3)2);Diacetoxypalladium;Bis(acetato)palladium;Acetic acid palladium salt;Diacetatopalladium;Palladium(2+) diacetate;HyCat Base 1;HyCat 1;3376-66-7;4854-43-7;24175-85-7;33571-36-7;125089-63-6;138823-54-8;1145835-48-8;1931145-94-6

  • Categories:

    Organic Chemistry  >  Organometallic Compounds

Description

brown needles

Palladium diacetate Basic Attributes

224.51

223.930099

222-164-4

0LTG3460Y5

28439090

Characteristics

80.3

-2.48760

Red-brown Various Forms In Red-(Powder/Flake/Crystalline/Beads)

180-181 °C

117.1ºC at 760mmHg

40ºC

H2O: insoluble ;soluble as monomer in glacial acetic acid or as trimer in benzene.

Store at R.T.

LD50 orally in Rabbit: >= 5110 mg/kg

Safety Information

3261

2

41-36/37/38-40-35

26-39-36/37/39-45-36

AJ1900000

Xi,Xn,C

Stable under normal temperatures and pressures.

P280-P305 + P351 + P338 + P310

H318

|Danger|H302 (72.4%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P272, P273, P280, P301+P312, P302+P352, P305+P351+P338, P310, P321, P330, P333+P313, P363, P391, and P501|Aggregated GHS information provided by 337 companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Drug Information

palladium(II) acetate

Palladium diacetate Use and Manufacturing

Methods of Manufacturing

Recycling palladium powder (10.3 g, 0.9 equiv) was added into AcOH (200 ml) and HNO3(0.5 ml), followed by refluxing for 30 min. When the reaction was stopped, the hot brownsolution was filtrated. The solution was concentrated until a little AcOH (~20 ml) was left.At room temperature, Pd(OAc)2 crystals precipitated at the bottom of beaker. Throughfiltration, we obtained recycling Pd(OAc)2 (20 g, 92percent).

Uses

A catalyst for intramolecular coupling.

Acetic acid, palladium salt (1:?): INACTIVE|Acetic acid, palladium(2+) salt (2:1): ACTIVE

Computed Properties

Molecular Weight:224.51
Hydrogen Bond Acceptor Count:4
Exact Mass:223.93009
Monoisotopic Mass:223.93009
Topological Polar Surface Area:80.3
Heavy Atom Count:9
Complexity:25.5
Covalently-Bonded Unit Count:3
Compound Is Canonicalized:Yes

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