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Home > Encyclopedia > Dicyclopentadiene diepoxide

Dicyclopentadiene diepoxide

Dicyclopentadiene diepoxide structure

Dicyclopentadiene diepoxide 

structure
  • CAS No:

    81-21-0

  • Formula:

    C10H12O2

  • Chemical Name:

    Dicyclopentadiene diepoxide

  • Synonyms:

    Bicyelopentadiene dioxide;BICYCLOPENTADIENE DIEPOXIDE;DICYCLOPENTADIENE DIEPOXIDE;DICYCLOPENTADIENE DIOXIDE;4,10-DIOXAPENTACYCLO[6.3.1.0(2,7).0(3,5).0(9,11)]DODECANE;DICYCLOPENTADIENE DIOXIDE, 97%, MIXTURE;Dicyclopentadienediepoxide,99%;2,4-Methano-2H-indeno1,2-b:5,6-bbisoxirene, octahydro-

  • Categories:

    Chemical Reagents  >  Organic Reagents

Description

white to yellow-beige crystals or


Poison by ingestion andintravenous routes. Mildly toxic by skin contact. A skinirritant. When heated to decomposition it emits acridsmoke and irritating fumes.

Dicyclopentadiene diepoxide Basic Attributes

164.2

164.20

112743

201-334-1

56357|54738|34460|30544|24262

TSCA listed

DTXSID4020452

White to yellow-beige

29109000

Characteristics

25.06000

1.01

White to yellow-beige Crystals or Crystalline Powder

1,331 g/cm3

185-189 °C(lit.)

120°C 10mm

120°C/10mm subl.

1.5460 (estimate)

Soluble in water.

4.77 @ 25 DEG C (AIR= 1)

LD50 orl-rat: 210 mg/kg UCDS** 10/5/61

Flammable; burning produces irritating fumes

MILD TERPENE LIKE ODOR MAY BE MASKED BY MORE POWERFUL & DISTINCTIVE HYDROCARBON ODOR OF DICYCLOPENTADIENE.

SUBLIMES @ 120-135 °C @ 10 MM HG

2-8°C

Safety Information

6.1

UN 2811 6.1/PG 3

3

Xn

26

PB9625200

Xn

Ventilated, low temperature and dry; stored separately from food materials in warehouse

P301 + P310-P305 + P351 + P338

22-36

UN 2811 6.1/PG 3

|Danger|H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]|P264, P270, P280, P301+P310, P305+P351+P338, P321, P330, P337+P313, P405, and P501|Aggregated GHS information provided by 44 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Toxicity

highly toxic

Drug Information

No cases of dermatitis or sensitization have been reported /in man/.

Dicyclopentadiene diepoxide Use and Manufacturing

Methods of Manufacturing

PROBABLY BY DIELS-ALDER CONDENSATION OF CYCLOPENTADIENE FOLLOWED BY EPOXIDATION.

Uses

INTERMEDIATE FOR EPOXY RESINS, PLASTICIZERS, PROTECTIVE COATINGS|RUBBER ADDITIVE, EG, FOR CRACK PREVENTION & ADHESION|For high temp & high performance system, adhesives


Dicyclopentadiene diepoxide acts as an intermediate for epoxy resins, plasticizers and protective coatings. It finds application as a rubber additive and adhesives, which is used at high temperature. Further, it is used in the preparation of endo-3-hydroxy-exo-9-oxa-exo-tetracyclo[5.3.1.02,6.08,10]undecane using lithium aluminum hydride as a reagent.

Production

(1979) PROBABLY GREATER THAN 2.72X10+6 G|(1980) PROBABLY GREATER THAN 2.72X10+6 G

2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-: ACTIVE|AVAIL IN EXPTL QUANT, THIS DIFUNCTIONAL EPOXIDE IS SUGGESTED FOR USE AS PRIMARY BUILDING BLOCK FOR EPOXY RESIN SYSTEM. IT HAS ALSO BEEN SUGGESTED IN MODIFICATION OF ALKYD RESINS, AS PLASTICIZER, & AS CHEMICAL INTERMEDIATE.

Computed Properties

Molecular Weight:164.20
XLogP3:0.8
Hydrogen Bond Acceptor Count:2
Exact Mass:164.083729621
Monoisotopic Mass:164.083729621
Topological Polar Surface Area:25.1
Heavy Atom Count:12
Complexity:277
Undefined Atom Stereocenter Count:8
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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