Sodium sesquicarbonate

226.03

189.94700

208-580-9

Y1X815621J

DTXSID6049646

White crystals, flakes, or crystalline powder|White, needle-shaped crystals

123.55000

-3.55930

DryPowder; DryPowder, Liquid; DryPowder, OtherSolid; DryPowder, PelletsLargeCrystals, OtherSolid, Liquid; Liquid; OtherSolid; PelletsLargeCrystals

2.112

Decomposes

Decomposes on heating by CO2 loss

Soluble in water

Odorless

Tasteless

Aqueous solutions are strongly alkaline. At 25 °C, the pH of 1, 5 and 10 wt% sodium carbonate solutions are 11.37, 11.58 and 11.70, respectively.

Monoclinic needles, density: 2.112. Crystals are stable in air. Solubility in water (g/100 mL) at 0 °C: 13; at 100 42. Aqueous solutions are mildly alkaline. pH of 0.1M solution = 10.1 /Sodium sesquicarbonate dihydrate/|Less alkaline than sodium cabonate|DOUBLE SALT OF SODIUM CARBONATE & SODIUM BICARBONATE|MP: decomposes; Index of Refraction: 1.5073 /Sodium sesquicarbonate dihydrate/

FG2099000

Crystals are stable in air /Sodium sesquicarbonate dihydrate/

P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501

H315

SRP: The most favorable course of action is to use an alternative chemical product with less inherent propensity for occupational harm/injury/toxicity or environmental contamination. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material's impact on air quality; potential migration in soil or water; effects on animal and plant life; and conformance with environmental and public health regulations.|SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Substance added directly to human food affirmed as generally recognized as safe (GRAS).|Sodium sesquicarbonate used as a general purpose food additive in animal drugs, feeds, and related products is generally recognized as safe when used in accordance with good manufacturing or feeding practice.

|Warning|H315 (17.57%): Causes skin irritation [Warning Skin corrosion/irritation]|P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 246 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]|Aggregated GHS information provided by 38 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|H315: Causes skin irritation [Warning Skin corrosion/irritation]

Irritating to skin and mucous membranes. Trona dust is alkaline (pH 10.5) and can have an irritant effect on respiratory airways, mucous membranes, and the skin.

The world's largest deposit of trona is in the Green River Basin of Wyoming. About 47 billion tons of identified soda ash resources could be recovered from the 56 billion tons of bedded trona and the 47 billion tons of interbedded or intermixed trona and halite that are in beds more than 1.2 meters thick. ... Searles Lake and Owens Lake in California contain an estimated 815 million tons of soda ash reserves(1).|About fifty to sixty million years ago, a shallow, expansive body of water called Lake Gosiute covered the Green River Basin in southwestern Wyoming. The area climate would cycle from wet to dry: wet periods would deposit mud on the lake bottom, while dry periods would precipitate trona and other saline minerals. Over a period of many years, these cycles left behind approximately 100 billion tons of nearly pure trona layered between beds of sandstone, marlstone and shale. The trona beds have a nearly horizontal orientation, similar to when they were originally deposited, at depths ranging from about 800 feet to 3500 feet below the surface. ... There are 25 major trona beds that occur within the Wilkins Peak Member of the Upper Eocene Age Green River Formation. The trona deposit as a whole covers about 1000 square miles within the Green River Basin, mostly in Sweetwater County, Wyoming.

Occurs native (as trona) in desert areas and Searles Lake brine /Mojave Desert, San Bernadino County, CA/|Found in nature as the dihydrate, e.g. Owens Lake, Searles Lake (U.S.A.); Lake Magadi (Kenya).|There are at least 62 identified naturally occurring sodium carbonate deposits in the world ...|Trona is a relatively rare sodium-rich mineral found in the United States, Africa, China, Turkey, and Mexico.

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Organic bases/Amines and related compounds/|Basic treatment: Establish a patent airway (oropharyngeal or nasopharyngeal airway, if needed). Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with 0.9% saline (NS) during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 ml of water for dilution if the patent can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal ... . Cover skin burns with dry sterile dressings after decontamination ... . /Organic bases/Amines and related compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious, has severe pulmonary edema, or is in severe respiratory distress. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Consider drug therapy for pulmonary edema ... . Monitor cardiac rhythm and treat arrhythmias as necessary ... . Start IV administration of D5W /SRP: "To keep open", minimal flow rate/. Use 0.9% saline (NS) or lactated Ringer's (LR) if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. If patient is unresponsive to these measures, vasopressors may be helpful. Watch for signs of fluid overload ... . Administer 1% solution methylene blue if patient is symptomatic with severe hypoxia, cyanosis, and cardiac compromise not responding to oxygen. ... . Treat seizures with diazepam or lorazepam ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Organic bases/Amines and related compounds/

/SURVEILLANCE/ Trona (sodium sesquicarbonate) is mined from an underground deposit in Wyoming and processed for use in glass, paper, detergent, and chemical applications. Trona dust is alkaline (pH 10.5) and can have an irritant effect on respiratory airways, mucous membranes, and the skin. A study population of 142 underground miners and 88 surface workers from one facility volunteered for an epidemiologic study. Their mean age was 37.6 yr and mean duration of employment was 10.0 yr. The percentage with chronic cough and phlegm was 23%; both symptoms were more common among smokers than nonsmokers. Thirty-three percent of the workers complained of dyspnea when hurrying on level ground or walking up a slight hill. Half of the workers complained of upper respiratory tract symptoms and eye irritation. Both smokers and exsmokers had significant declines of forced expiratory volume in 1 sec (FEV1.0) with age; exsmokers also had declines with work-years when compared to a nonsmoking comparison population. Nonsmokers with personal dust measurements had a significant decline of FEV1.0 related to respirable dust exposure. A shift study of 104 workers revealed a significant fall in FEV1.0 among nonsmokers and surface workers. Significance was approached in the high dust exposure group. An increase in the mean percent predicted forced vital capacity and FEV1.0 was shown for the 125 workers who had a 5-yr follow-up of pulmonary function. There was no correlation between the shift study decrements and the longitudinal 5-yr follow-up. Industrial hygiene dust sampling found elevated levels of total dust but lower respirable dust, with no detectable free silica.

Magadi soda

Grades: Technical; Food Chemical Codex

Carbonic acid, sodium salt (2:3): ACTIVE|Trona ore, a naturally occurring impure sodium sesquicarbonate|Underground room-and-pillar mining, using conventional and continuous mining, is the primary method of mining Wyoming trona ore.|Wyoming trona resources are being depleted at the rate of about 15 million tons per year (8.3 million tons of soda ash.

CARBONATE & HYDROXIDE- ACID TITRATION. /SODIUM CARBONATE/|OSW Method No. 7770 Sodium (Atomic Absorption, Direct Aspiration). Flame atomic absorption spectrometry (FLAA) Detection Limit = 0.0020 mg/L /Sodium/|USGS Method No. I1735-S, -W Sodium, Atmoic Absorption Spectrometric, Direct. Flame atomic absorption spectrometry (FLAA) Detection Limit = 10 mg/kg in soil, 0.010 mg/L in water; See also Method Numbers I3736, I5473, and I5474 /Sodium/|NIOSH Method 7300, Elements (ICP), issued 2-15-84. Inductively Coupled Argon Plasma, Atomic Emission Spectroscopy, detection limit = 2.5 to 1,000 ug per sample /Sodium/|Studies on the assay of carbonate or bicarbonate in phramaceutical preparations by ion chromatography /Bicarbonate/

EPA Safer Chemical Functional Use Classes -> Processing Aids and Additives|Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern|Food additives|Food Additives -> ACIDITY_REGULATOR; -> JECFA Functional Classes|Cosmetics -> Buffering; Bulking; Cleansing

Food Additives -> ACIDITY_REGULATOR;