9-ACETYLCARBAZOLE97
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9-ACETYLCARBAZOLE97
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CAS No:
574-39-0
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Formula:
C14H11NO
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Chemical Name:
9-ACETYLCARBAZOLE97
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Synonyms:
9-Acetylcarbazole;1-(9H-carbazol-9-yl)ethanone;9H-Carbazole, 9-acetyl-;1-Carbazol-9-yl-ethanone;9-acetyl-9H-carbazole;1-carbazol-9-ylethanone;9-acetyl-carbazole;1-(9H-carbazol-9-yl)ethan-1-one;UNII-J45K05W8L6;J45K05W8L6
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CAS No:
Safety Information
3
22-36/37/38
26-36
Xn
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
H302
|Warning|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, and P501|Aggregated GHS information provided by 38 companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
9-ACETYLCARBAZOLE97 Use and Manufacturing
General procedure: A mixture of [Ir(Cl)(cod)]2 (6.7 mg, 0.01 mmol), Na2CO3 (127 mg, 1.2 mmol), 1a (167 mg, 1 mmol) and 2 (430 mg, 5mmol) in Toluene (1 mL) was stirred at 100 °C for 15 h under Ar. The conversions and yields of products were estimated from peak areas based on an internal standard using GC and the product 3a was obtained in 96percent. The product 3a was isolated by column chromatography (230-400 mesh silica gel neutralized with 5percent Et3N in n-hexane) and in94percent yield (181 mg). The product 3e was only isolated by column chromatography (70-230 mesh aluminium oxide, n-hexane).
Computed Properties
Molecular Weight:209.24
XLogP3:3.2
Hydrogen Bond Acceptor Count:1
Exact Mass:209.084063974
Monoisotopic Mass:209.084063974
Topological Polar Surface Area:22
Heavy Atom Count:16
Complexity:267
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
