Copper carbonate
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Copper carbonate
structure -
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CAS No:
1184-64-1
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Formula:
CH2O3.Cu
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Chemical Name:
Copper carbonate
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Synonyms:
Carbonic acid,copper(2+) salt (1:1);Cupric carbonate (1:1);Copper carbonate (CuCO3);Copper carbonate (1:1);Copper carbonate;Copper monocarbonate;Cupric carbonate;Copper(II) carbonate (CuCO3)
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CAS No:
Copper carbonate Basic Attributes
215.5626
122.914345
214-671-4
9AOA5F11GJ
DTXSID6034471|DTXSID6058473
Characteristics
63.2
-2.44950
green or blue powder
200ºC
333.6°C at 760 mmHg
169.8ºC
insoluble H2O
2.58E-05mmHg at 25°C
Oral-Mouse LDL0: 320 mg/kg
Thermal decomposition to emit toxic copper-containing fumes
Green powder; den: 3.7 - 4.0; decomposes at 200 °C. Soluble in acids; insoluble in water /Basic/
Safety Information
Ⅲ
3077
9
The warehouse is low-temperature, ventilated and dry
Stable. Incompatible with strong acids.
P264, P270, P273, P301+P312, P330, P391, P501
H302
SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.
Trace minerals added to animal feeds. These substances added to animal feeds as nutritional dietary supplements are generally recognized as safe when added are levels consistent with good feeding practice. Element: Copper; Source compound: copper carbonate. (All substances listed may be in anhydrous or hydrated form.)
|Warning|H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]|P264, P270, P273, P301+P312, P330, P391, and P501|Aggregated GHS information provided by 133 companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.|SRP: Local exhaust ventilation should be applied wherever there is an incidence of point source emissions or dispersion of regulated contaminants in the work area. Ventilation control of the contaminant as close to its point of generation is both the most economical and safest method to minimize personnel exposure to airborne contaminants.
Verdigris, formed by atmospheric corrosion of the surface of metallic copper presumably composed of copper carbonates & oxides, causes immediate irritation & conjunctival inflammation when accidentally dropped or dusted on the eyes of patients but the reaction subsides without permanent damage soon after the eye is cleaned by irrigation. ... /Verdigris/
Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 1 mg/cu m. /Copper dusts and mists (as Cu)/
Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 1 mg/cu m. /Copper (dusts and mists)/
Toxicity
highly toxic
LD50 Rat oral 159 mg/kg bw [equivalent copper dose: 82 mg Cu/kg body weight] /from table/
Drug Information
MEDICATION (VET): ANTHELMINTIC AID IN SHEEP
Rats were fed a diet contain basic cupric carbonate, at doses of 0, 70, 220, 670 and 2,000 ppm as cupric hydroxide and 12 months, the levels of copper in the blood and tissues were determined by atomic absorption analysis. At the same time, fluctuations in the levels of iron and zinc, which are essential elements, were determined in the tissues. Levels of copper, iron and zinc in blood were practically unchanged after feeding for 12 months at the highest dose, 2000 ppm. Copper in the liver increased markedly at doses of 670 and 2000 ppm from 1 month, and the level reached about 50 times that of the control group. The level of copper in the kidney significantly increased at larger doses than 670 ppm. Iron concentration in the kidney did not change at smaller doses than 220 ppm, but significantly decreased at higher doses than 670 ppm. The level of copper in the kidney increased only at the highest dose. /Basic cupric carbonate/
Verdigris, formed by atmospheric corrosion of the surface of metallic copper presumably composed of copper carbonates & oxides, causes immediate irritation & conjunctival inflammation when accidentally dropped or dusted on the eyes of patients, but the reaction subsides without permanent damage soon after the eye is cleaned by irrigation. /Verdigris/
copper carbonate
Copper carbonate Use and Manufacturing
By adding sodium carbonate to a solution of copper sulfate, filtering and drying. /Basic/
For Copper(II) carbonate (USEPA/OPP Pesticide Code: 022901) ACTIVE products with label matches. /SRP: Registered for use in the U.S. but approved pesticide uses may change periodically and so federal, state and local authorities must be consulted for currently approved uses./|MEDICATION|MEDICATION (VET)|IN ANIMAL & POULTRY FEEDS AS READILY ABSORBABLE SOURCE OF COPPER|Pigments, pyrotechnics, insecticides, copper salts, coloring brass black, astringent in pomade preparations, antidote for phosphorus poisoning, smut preventive, fungicide for seed treatment, feed additive (in small amounts) /Basic/
USEPA/OPP Pesticide Code 022901; Trade Names: Malachite; Bremen green; Bremen blue.|Grade: Technical, CP /Basic/
Carbonic acid, copper(2+) salt (1:1): ACTIVE
Computed Properties
Molecular Weight:123.55
Hydrogen Bond Acceptor Count:3
Exact Mass:122.914341
Monoisotopic Mass:122.914341
Topological Polar Surface Area:63.2
Heavy Atom Count:5
Complexity:18.8
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes
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