Platinum dioxide
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Platinum dioxide
structure -
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CAS No:
1314-15-4
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Formula:
O2Pt
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Chemical Name:
Platinum dioxide
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Synonyms:
Platinum oxide (PtO2);Adams' catalyst;Platinic oxide;Platinum dioxide;Platinum(IV) oxide;NSC 402624
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CAS No:
Characteristics
34.14000
-0.24010
Dark brown crystalline
10.2
450 °C(lit.)
soluble in caustic potash solution. Insoluble in water, acid, aquaregia.
Store in a cool, dry place. Store in a tightly closed container.
Safety Information
II
5.1
UN 1479 5.1/PG 2
2
8-36-41-38-36/37/38
26-36/37/39-28A-22-17-36
TP2506020
O,Xi
Contact with combustible material may cause fire. Incompatible with organic materials, powdered metals.
P220-P305 + P351 + P338
H272-H319
|Danger|H271 (68.98%): May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]|P210, P220, P221, P264, P280, P283, P305+P351+P338, P306+P360, P337+P313, P370+P378, P371+P380+P375, and P501|Aggregated GHS information provided by 226 companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Platinum dioxide Use and Manufacturing
As catalyst in hydrogenations.The actual catalyst is platinum black which is formed in situ by reduction of the PtO2 by the hydrogen used for the hydrogenation.Especially useful for reduction at room tempereture and hydrogen pressures up to 4 atmospheres.Suitable for the reduction of double and triple bonds, aromatic nuclei, carbonyl groups, nitro groups, and nitriles.
Platinum oxide (PtO2): ACTIVE
Computed Properties
Molecular Weight:227.08
Hydrogen Bond Acceptor Count:2
Exact Mass:226.954624
Monoisotopic Mass:226.954624
Topological Polar Surface Area:34.1
Heavy Atom Count:3
Complexity:18.3
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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