Benzenesulfonic acid, 3-nitro-, sodium salt (1:1)
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Benzenesulfonic acid, 3-nitro-, sodium salt (1:1)
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CAS No:
127-68-4
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Formula:
C6H5NO5S.Na
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Chemical Name:
Benzenesulfonic acid, 3-nitro-, sodium salt (1:1)
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Synonyms:
Benzenesulfonic acid,3-nitro-,sodium salt (1:1);Benzenesulfonic acid,m-nitro-,sodium salt;Benzenesulfonic acid,3-nitro-,sodium salt;Nitrol S;Nacan;Sodium m-nitrobenzenesulfonate;Sodium 3-nitrobenzenesulfonate;m-Nitrobenzenesulfonic acid sodium salt;Ludigol;3-Nitrobenzenesulfonic acid sodium salt;m-Nitrobenzenesulfonic acid sodium salt;Sodium m-nitrobenzenesulfonate;Sodium 3-nitrophenylsulfonate;Register liquid;Resist S;Fangranyan S;Resist salt L;55945-59-0
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CAS No:
Benzenesulfonic acid, 3-nitro-, sodium salt (1:1) Basic Attributes
225.15
224.970779
204-857-3
1F11SXJ4C6
DTXSID2027048
29049085
Characteristics
111
-2.61 (LogP)
Light yellow Crystalline Powder
0.45 g/cm3 (20 °C)
52.3 °C
217.5 °C
100 °C
water: soluble 50mg/mL, clear to slightly hazy, faintly yellow to yellow
Store below +30°C.
LD50 orally in Rabbit: > 2000 mg/kg
Safety Information
NONH for all modes of transport
1
36-43
24-26-37
DB7195000
Xi
Stable. Hygroscopic. Incompatible with strong oxidizing agents.
P280-P305 + P351 + P338
H317-H319
|Warning|H317: May cause an allergic skin reaction [Warning Sensitization, Skin]|P261, P264, P272, P280, P302+P352, P305+P351+P338, P321, P333+P313, P337+P313, P363, and P501|H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]|Aggregated GHS information provided by 691 companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Benzenesulfonic acid, 3-nitro-, sodium salt (1:1) Use and Manufacturing
In the enamel kettle, first add 350 parts of fuming sulfuric acid, control the temperature of the kettle to 0~5℃, slowly add nitrobenzene under stirring, add 132 parts of nitrobenzene within 1h, and raise the temperature of the kettle to 100℃, keep warm 2h. Sampling to measure the end point of sulfonation (drop 1 to 2 drops of material into a 10ml test tube filled with clear water, and no turbidity proves to the end). After the sulfonation reaction is completed, it is cooled, slowly added to ice water, and 2,000 parts of common salt are added in about 3 hours. After salting out for a few hours, it is allowed to stand overnight, suction filtered, and dried to obtain intermediate m-nitrobenzenesulfonic acid. Put m-nitrobenzene sulfonic acid into 500 parts of hot water and boil to dissolve. Remove a small amount of sulfone. Add 50 parts of soda ash for neutralization, then add activated carbon for decolorization, filter while hot, and cool the filtrate to crystallize. After the filter cake is washed with a small amount of water, it is dried below 50°C to obtain the finished product.
Sodium m-nitrobenzenesulfonate is used as anti-staining agent for vat dyes, sulfur dyes and color-forming protective agents for dyes, rust remover for ships and nickel remover for electroplating, and is also an intermediate for dyes and vanillin.
Finishing agents
Metal products not covered elsewhere
1,000,000 - 10,000,000 lb
All other basic organic chemical manufacturing|Benzenesulfonic acid, 3-nitro-, sodium salt (1:1): ACTIVE
Cosmetics -> Viscosity controlling
Computed Properties
Molecular Weight:225.16
Hydrogen Bond Acceptor Count:5
Exact Mass:224.97078768
Monoisotopic Mass:224.97078768
Topological Polar Surface Area:111
Heavy Atom Count:14
Complexity:274
Covalently-Bonded Unit Count:2
Compound Is Canonicalized:Yes
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Benzenesulfonic acid, 3-nitro-, sodium salt (1:1)
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