DL-10-CAMPHORSULFONIC ACID
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DL-10-CAMPHORSULFONIC ACID
structure -
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CAS No:
5872-08-2
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Formula:
C10H16O4S
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Chemical Name:
DL-10-CAMPHORSULFONIC ACID
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Synonyms:
DL-10-CAMPHORSULPHONIC ACID;DL-10-CAMPHORSULFONIC ACID;DL-10-CAMPHORSULFONIC ACID N-HYDRATE;D-(+)-10-CAMPHORSULFONIC ACID MONOHYDRATE;(+/-)-CAMPHOR-10-SULPHONIC ACID;(+/-)-CAMPHOR-10-SULFONIC ACID (BETA);(+/-)-CAMPHOR-10-SULFONIC ACID;CAMPHOR-10-SULFONIC ACID
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CAS No:
Description
DL-Camphorsulfonic acid, also known as camphorsulfonic acid, is a white or almost white crystalline powder. The molecular formula of camphorsulfonic acid is C10H16O4S. It is a pair of chiral optical enantiomers with prismatic crystals, divided into left-handed camphorsulfonic acid and right-handed camphorsulfonic acid. The melting point is 193~195 ℃ and 197~200 ℃, respectively. Camphorsulfonic acid is a derivative of camphor, widely used in medicine, light industry and cosmetic industry. At pre
DryPowder
Camphorsulfonic acid is a sulfonic acid containing the camphorsulfonate anion. It derives from a camphor. It is a conjugate acid of a camphorsulfonate anion.
DL-10-CAMPHORSULFONIC ACID is white to off-white powder
Camphorsulfonic acid is a organosulphur compound.
DL-10-CAMPHORSULFONIC ACID Basic Attributes
232.3
232.30
3205973
227-527-0
TSCA listed
Slightly beige
29147000
Characteristics
79.82000
0.5
Slightly beige Granular Powder
1.2981 (rough estimate)
203-206 °C (dec.)(lit.)
344.46°C (rough estimate)
1.5400 (estimate)
Soluble in water.
2-8°C
1.17±0.50(Predicted)
2-8°C
Safety Information
III
8
UN 3261 8/PG 2
3
C
26-36/37/39-45-27
DT5077100
C
Stable. Incompatible with strong bases, strong oxidizing agents. Combustible.
P260-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
34
UN 3261 8/PG 2
|Danger|H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]|P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, and P501|Aggregated GHS information provided by 68 companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.|Aggregated GHS information provided by 54 companies from 5 notifications to the ECHA C&L Inventory.
DL-10-CAMPHORSULFONIC ACID Use and Manufacturing
Pharmaceutical intermediate or isomer product resolution
Pharmaceutical intermediates, optical split agent. Camphorsulfonic acid is an important organic synthesis intermediates, optical resolving agent. Due to its optical rotation, it is industrially applicable be the optical isomers for racemisation, and is also widely used as pharmaceutical intermediates such as for the production of intestinal disorder inhibitors, HIV improving agents and the like. Left and right handed camphorsulfonic acid is an important resolving agent for optically active amino acids, such as camphorsulfonic acid—a chiral ion-pairing reagent. It separates 5 substances—phenylpropanolamine, which has receptor-blocking action and cardiac inhibition and local anesthetic action effects; metoprolol, propranolol, epinephrine, salbutamol and atenolol.Camphor sulfonate made by camphorsulfonic acid for salting or other synthetic routes also has a wide range of uses. For example, camphor sulfonate is a veterinary central stimulant, which can stimulate the respiratory center and cause respiratory excitement, ; it is used for the treatment respiratory and circulatory acute disorders, resisting central nervous system poisoning; camphor ammonium sulfonate acts as a chiral ion pair reagent added to the mobile phase to separate the aromatic alcohol amine drug enantiomers.Figure 3: Camphor sulfonate
(+)-Camphor-10-sulfonic acid is used as a resolving agent for chiral amines and other cations. It is involved in the preparation of active pharmaceutical ingredient such as trimetaphan camsilate, which is used to reduce bleeding during neurosurgery. Further, it is involved in the transglucosidation of methyl and ethyl D-glucopyranosides by alcoholysis.
25,000 - 100,000 lb
Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-: ACTIVE|Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S,4R)-: ACTIVE
Computed Properties
Molecular Weight:232.30
XLogP3:0.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:232.07693016
Monoisotopic Mass:232.07693016
Topological Polar Surface Area:79.8
Heavy Atom Count:15
Complexity:404
Undefined Atom Stereocenter Count:2
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes
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