Ferbam Safety Data Sheets
SAFETY DATA SHEETS
According to the UN GHS revision 8
SECTION 1: Identification
1.1 GHS Product identifier
| Product name | Ferbam |
|---|
1.2 Other means of identification
| Product number | - |
|---|---|
| Other names | Aaferzimag; Ferric Dimethyldithiocarbamate; N,N-dimethylcarbamodithioate,iron(3+) |
1.3 Recommended use of the chemical and restrictions on use
| Identified uses | Industrial and scientific research uses. |
|---|---|
| Uses advised against | no data available |
1.4 Supplier's details
| Company | Echemi.com |
|---|---|
| Address | Echemi.com |
| Telephone | Echemi.com |
1.5 Emergency phone number
| Emergency phone number | Echemi.com |
|---|---|
| Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
SECTION 2: Hazard identification
2.1 Classification of the substance or mixture
Skin irritation, Category 2
Eye irritation, Category 2
Specific target organ toxicity â single exposure, Category 3
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
2.2 GHS label elements, including precautionary statements
| Pictogram(s) |   |
|---|---|
| Signal word | Warning |
| Hazard statement(s) | H315 Causes skin irritation H319 Causes serious eye irritation H335 May cause respiratory irritation H410 Very toxic to aquatic life with long lasting effects |
| Precautionary statement(s) | |
| Prevention | P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. |
| Response | P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P317 If skin irritation occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P319 Get medical help if you feel unwell. P391 Collect spillage. |
| Storage | P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. |
| Disposal | P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
2.3 Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
3.1 Substances
| Chemical name | Common names and synonyms | CAS number | EC number | Concentration |
|---|---|---|---|---|
| Ferbam | Ferbam | 14484-64-1 | 238-484-2 | 100% |
SECTION 4: First-aid measures
4.1 Description of necessary first-aid measures
If inhaled
Fresh air, rest. Refer for medical attention.
Following skin contact
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Following eye contact
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Following ingestion
Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .
4.2 Most important symptoms/effects, acute and delayed
Exposure Routes: inhalation, ingestion, skin and/or eye contact Symptoms: Irritation eyes, respiratory tract; dermatitis; gastrointestinal disturbance Target Organs: Eyes, skin, respiratory system, gastrointestinal tract (NIOSH, 2016)
4.3 Indication of immediate medical attention and special treatment needed, if necessary
Wash contaminating chemical from skin and hair with soap and water. Persons sensitive to thiram (rubber-sensitive) should be permanently removed from contact with compounds of this nature. Flush contaminant from eyes with fresh water for 10-15 minutes. If thiram or metallo dithiocarbamate compounds have been ingested: a) if vigorous emesis has not already occurred and victim is fully alert, give syrup of ipecac, followed by 1-2 glasses of water to induce vomiting (adults, 12 yr and older: 30 mL; children under 12: 15 mL). If consciousness level declines or vomiting has not occurred in 15 minutes, empty the stomach by intubation, aspiration, and lavage. Dithiocarbamates and Thiocarbamates
SECTION 5: Fire-fighting measures
5.1 Suitable extinguishing media
Use/ water spray, powder.
5.2 Specific hazards arising from the chemical
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. (ERG, 2016)
5.3 Special protective actions for fire-fighters
Use water spray, powder.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.
6.2 Environmental precautions
Sweep spilled substance into covered sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. Personal protection: particulate filter respirator adapted to the airborne concentration of the substance.
6.3 Methods and materials for containment and cleaning up
Ventilate area of spill. Collect spilled material in the most convenient and safe manner and deposit in sealed containers for reclamation, or for disposal in a secured sanitary landfill. Liquid containing ferbam should be absorbed in vermiculite, dry sand, earth, or a similar material.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
7.2 Conditions for safe storage, including any incompatibilities
Separated from strong oxidants, copper compounds, mercury compounds, alkaline materials and food and feedstuffs. Dry. Well closed.Store in cool, dry, well-ventilated, secure area out of reach of children and animals.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational Exposure limit values
TLV: (inhalable fraction): 5 mg/m3, as TWA; A4 (not classifiable as a human carcinogen)
Biological limit values
no data available
8.2 Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
8.3 Individual protection measures, such as personal protective equipment (PPE)
Eye/face protection
Wear safety spectacles.
Skin protection
Protective gloves. Protective clothing.
Respiratory protection
Use local exhaust or breathing protection.
Thermal hazards
no data available
SECTION 9: Physical and chemical properties and safety characteristics
| Physical state | Ferbam is a dark brown to black odorless solid. Used as a fungicide. (NIOSH, 2016) |
|---|---|
| Colour | Black or dark-colored fluffy powder |
| Odour | Odorless |
| Melting point/freezing point | 66°C(lit.) |
| Boiling point or initial boiling point and boiling range | 98°C/19mmHg(lit.) |
| Flammability | Combustible Solid |
| Lower and upper explosion limit/flammability limit | no data available |
| Flash point | 9°C(lit.) |
| Auto-ignition temperature | no data available |
| Decomposition temperature | 180°C |
| pH | pH = 5.0 |
| Kinematic viscosity | no data available |
| Solubility | 0.01 % (NIOSH, 2016) |
| Partition coefficient n-octanol/water | log Kow = -1.60 |
| Vapour pressure | 0 mm Hg (approx) (NIOSH, 2016) |
| Density and/or relative density | approx 0.6 kg/L |
| Relative vapour density | no data available |
| Particle characteristics | no data available |
SECTION 10: Stability and reactivity
10.1 Reactivity
Decomposes on heating and on contact with moisture. This produces toxic and flammable gases. Reacts with strong oxidants.
10.2 Chemical stability
Tends to decompose on prolonged storage or exposure to heat and moisture.
10.3 Possibility of hazardous reactions
It should be kept away from ignition sources because the decomp products are flammable.FERBAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Strong oxidizers, moisture.
10.6 Hazardous decomposition products
When heated to decomposition it emits very toxic fumes of nitrogen and sulfur oxides.
SECTION 11: Toxicological information
Acute toxicity
- Oral: LD50 Rat oral 1130 mg/kg
- Inhalation: LC50 Rat inhalation 0.4 mg/L/4 hr
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
Classification of carcinogenicity: 1) evidence in humans: No adequate data; 2) evidence in animals: Inadequate data. Overall summary evaluation of carcinogenic risk to humans is Group 3: The agent is not classifiable as to its carcinogenicity to humans. From table
Reproductive toxicity
no data available
STOT-single exposure
The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the central nervous system.
STOT-repeated exposure
Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the nervous system and thyroid.
Aspiration hazard
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
SECTION 12: Ecological information
12.1 Toxicity
- Toxicity to fish: LC50 Salmo gairdneri (Rainbow trout, early life stages from the fertilized egg to the early fry stage) 2.9 ug/L/60 day (95% confidence interval: 2.7-3.2 ug/L); renewal
- Toxicity to daphnia and other aquatic invertebrates: LC50 Daphnia magna 0.09 mg/L/48 hr /Conditions of bioassay not specified in source examined
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
12.2 Persistence and degradability
AEROBIC: In pH 3.4 sandy soil, ferbam was largely decomposed after 4 to 5 weeks, while in pH 7.0 soil ferbam was decomposed after 14 to 15 weeks(1). Ferbam took longer than 8 weeks to reach the half-decay point in humus sandy soils as determined by activity to Rhizoctonia solani. If the humus content was 1.2% or below, an initial lag in the start of decomposition was observed(2). Ferbam releases carbon disulfide when it decomposes in soil(3).
12.3 Bioaccumulative potential
An estimated BCF of 3 was calculated for ferbam(SRC), using a log Kow of -1.60(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC), provided the compound is not altered physically or chemically once released into the environment.
12.4 Mobility in soil
The Koc of ferbam is estimated as 300(SRC), using a water solubility of 130 mg/L(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that ferbam is expected to have moderate mobility in soil. Using a soil TLC system (Hagerstown silty clay loam, 2.5% organic matter, 39.5% clay, pH 6.8) visualized by bioautography with 10 soil fungi and one alga, mean Rf values for analytical grade ferbam were 0.93, 0.64, 0.36, and 0.0(4).
12.5 Other adverse effects
no data available
SECTION 13: Disposal considerations
13.1 Disposal methods
Product
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
14.1 UN Number
| ADR/RID: UN2811 (For reference only, please check.) | IMDG: UN2811 (For reference only, please check.) | IATA: UN2811 (For reference only, please check.) |
14.2 UN Proper Shipping Name
| ADR/RID: TOXIC SOLID, ORGANIC, N.O.S. (For reference only, please check.) | IMDG: TOXIC SOLID, ORGANIC, N.O.S. (For reference only, please check.) | IATA: TOXIC SOLID, ORGANIC, N.O.S. (For reference only, please check.) |
14.3 Transport hazard class(es)
| ADR/RID: 6.1 (For reference only, please check.) | IMDG: 6.1 (For reference only, please check.) | IATA: 6.1 (For reference only, please check.) |
14.4 Packing group, if applicable
| ADR/RID: I (For reference only, please check.) | IMDG: I (For reference only, please check.) | IATA: I (For reference only, please check.) |
14.5 Environmental hazards
| ADR/RID: Yes | IMDG: Yes | IATA: Yes |
14.6 Special precautions for user
no data available
14.7 Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations specific for the product in question
| Chemical name | Common names and synonyms | CAS number | EC number |
|---|---|---|---|
| Ferbam | Ferbam | 14484-64-1 | 238-484-2 |
| European Inventory of Existing Commercial Chemical Substances (EINECS) | Listed. | ||
| EC Inventory | Listed. | ||
| United States Toxic Substances Control Act (TSCA) Inventory | Listed. | ||
| China Catalog of Hazardous chemicals 2015 | Not Listed. | ||
| New Zealand Inventory of Chemicals (NZIoC) | Listed. | ||
| Philippines Inventory of Chemicals and Chemical Substances (PICCS) | Not Listed. | ||
| Vietnam National Chemical Inventory | Listed. | ||
| Chinese Chemical Inventory of Existing Chemical Substances (China IECSC) | Listed. | ||
| Korea Existing Chemicals List (KECL) | Listed. | ||
SECTION 16: Other information
Information on revision
| Creation Date | July 15, 2019 |
|---|---|
| Revision Date | July 15, 2019 |
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Other Information
The substance is combustible but no flash point is available in literature.Exposure to Ferbam may cause alcohol intolerance.Depending on the degree of exposure, periodic medical examination is suggested.Carrier solvents used in commercial formulations may change physical and toxicological properties.Ferbam is often used in combinations with dithiocarbamates.
Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.
Ferbam is included in Bulk Drug Intermediates category.
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