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Mike West

Are decomposition and dissociation reactions the same?

Andras Ivan  Follow

Decomposition and disassociation refer to similar processes, however they are different. The main difference between them is that decomposition reactions are usually irreversible while disassociation reactions are reversible and exist in equilibrium.

A decomposition reaction is where a compound breaks up into smaller elements or compounds. For example: $$\ce{2H2O -> 2H2 + O2}$$ is an example of a decomposition reaction. Note that in this case that this is actually a reversible reaction.

A disassociation reaction is the general process where molecules split into smaller particles which can include elements, compounds, ions and radicals. For example: $$\ce{NaCl(s) -> Na+ (aq) + Cl- (aq)}$$ is a disassociation reaction.

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Gilker Kimmel  Follow
Thanks for pointing that out. I have edited my answer now.More
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Jayna Stokes  Follow
they partially overlap - decomposition can proceed via dissotiationMore
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Jon Mixon  Follow
Your example of a "decomposition" reaction is not very "irreversible", in fact the opposite: the reverse reaction (hydrogen combustion) that is irreversible. It isnt really accurate to classify reactions by their reversibility.More
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