I don't understand why calcium oxalate would dissolve in a sulfuric acid solution. CaC2O4 + 2H+ + SO42- H2C2O4 + CaSO4
You should compare solubility products and Ka values to see if the protonation of oxalate shifts the dissolution far enough to the right, and to see whether concentration of Ca2+ gets high enough to guarantee CaSO4 precipitation.
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I can't understand this step(edited) 5C2O42- + 2MnO4- + 16H+ 10CO2 + 2Mn2+ + 8H2O Is the following step and it's just as confusing. I can't seem to understand why these reactions happen, specifically why CO2 is formed.
That's just the way it is, oxalate gets oxidized by a strong oxidizer (permanganate). Not sure what kind of understanding do you seek here.
I don't understand why calcium oxalate would dissolve in a sulfuric acid solution. CaC2O4 + 2H+ + SO42- H2C2O4 + CaSO4
You should compare solubility products and Ka values to see if the protonation of oxalate shifts the dissolution far enough to the right, and to see whether concentration of Ca2+ gets high enough to guarantee CaSO4 precipitation.
Quote
I can't understand this step(edited) 5C2O42- + 2MnO4- + 16H+ 10CO2 + 2Mn2+ + 8H2O Is the following step and it's just as confusing. I can't seem to understand why these reactions happen, specifically why CO2 is formed.
That's just the way it is, oxalate gets oxidized by a strong oxidizer (permanganate). Not sure what kind of understanding do you seek here.
You should determine calcium in your sample by indirect manganometric titration of oxalate from calcium oxalate. In the first step, you precipitate calcium by ammonium oxalate from your sample (eg calcium Vit.C tablets). Then you dissolve pure calcium oxalate in diluted sulfuric acid suitable for manganometry. In the final step, you titrate oxalic acid with potassium permanganate using well-known reaction, which is quantitative. In this reaction carbon dioxide always evolves. From the last reaction, you can easily calculate the amount of oxalate bonded by calcium, and from the molar equivalence of calcium and oxalate ==> amount of calcium.
You should determine calcium in your sample by indirect manganometric titration of oxalate from calcium oxalate. In the first step, you precipitate calcium by ammonium oxalate from your sample (eg calcium Vit.C tablets). Then you dissolve pure calcium oxalate in diluted sulfuric acid suitable for manganometry. In the final step, you titrate oxalic acid with potassium permanganate using well-known reaction, which is quantitative. In this reaction carbon dioxide always evolves. From the last reaction, you can easily calculate the amount of oxalate bonded by calcium, and from the molar equivalence of calcium and oxalate ==> amount of calcium.
You should compare solubility products and Ka values to see if the protonation of oxalate shifts the dissolution far enough to the right, and to see whether concentration of Ca2+ gets high enough to guarantee CaSO4 precipitation.
Quote
That's just the way it is, oxalate gets oxidized by a strong oxidizer (permanganate). Not sure what kind of understanding do you seek here.
You should compare solubility products and Ka values to see if the protonation of oxalate shifts the dissolution far enough to the right, and to see whether concentration of Ca2+ gets high enough to guarantee CaSO4 precipitation.
Quote
That's just the way it is, oxalate gets oxidized by a strong oxidizer (permanganate). Not sure what kind of understanding do you seek here.
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In the first step, you precipitate calcium by ammonium oxalate from your sample (eg calcium Vit.C tablets).
Then you dissolve pure calcium oxalate in diluted sulfuric acid suitable for manganometry.
In the final step, you titrate oxalic acid with potassium permanganate using well-known reaction, which is quantitative. In this reaction carbon dioxide always evolves.
From the last reaction, you can easily calculate the amount of oxalate bonded by calcium, and from the molar equivalence of calcium and oxalate ==> amount of calcium.
In the first step, you precipitate calcium by ammonium oxalate from your sample (eg calcium Vit.C tablets).
Then you dissolve pure calcium oxalate in diluted sulfuric acid suitable for manganometry.
In the final step, you titrate oxalic acid with potassium permanganate using well-known reaction, which is quantitative. In this reaction carbon dioxide always evolves.
From the last reaction, you can easily calculate the amount of oxalate bonded by calcium, and from the molar equivalence of calcium and oxalate ==> amount of calcium.
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VOTE