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Liran Crownyse

Comparing Ammonium Sulfate to Ammonium Bisulfate

Barbara S. Reeves  Follow
I would like to confirm a point you made.
From your recollection for about a week on WIKIPEDIA the value for the boiling point of Ammonium Sulfate was substantially different than what is now posted on that site.
I just want to make sure I correctly understand your post.

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Charlie  Follow
Quote from:
I read that ammonium sulfate decomposes at 212 (strange same temp water boils...) to I guess ammonium bisulfate.  I would suspect that a scent of ammonia would emminate from the heated solution if that happens? 

First of all:

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Ammonium sulfate decomposes upon heating above 250 °C, first forming ammonium bisulfate. Heating at higher temperatures results in decomposition into ammonia, nitrogen, sulfur dioxide, and water.[13]
  from Wikipedia:  https://en.wikipedia.org/wiki/Ammonium_sulfate#Reactions

And I'm sure they mean dry, since a water solution can't become hotter than its boiling point.  So, decomposition with gentle heat shouldn't be a problem.

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Don Forcash  Follow
Thanks for the reply.  I know I saw the 100 deg C on the page for about a week.  The first time I reviewed it I saw what is there now with the 450 deg F range.  I verified it probably  10 times as I was really confused.  I may have a saved PDF of the page I will look for. 

On another note, there are a number of references to the 100C temp as well. 


https://www.google.com/url?sa=t&rct=j&q=&esrc=s&source=web&cd=4&cad=rja&uact=8&ved=0ahUKEwiphsr2ruDKAhXGzz4KHcgJDysQFggvMAM&url=http%3A%2F%2Fcelbar.com%2Fwp-content%2Fthemes%2Fcelbar%2Fassets%2Fpdf%2FAmmonium%2520Sulfate.pdf&usg=AFQjCNFn7cuhNAPQmpwoaeo5VGhji7YxhA&sig2=vJciWHLsrootVBbT5vV-qQ&bvm=bv.113370389,d.cWw


https://www.reddit.com/r/chemhelp/comments/3cgpd7/ammonium_sulphate_decomposition/

Anyway, is there a good source for finding elements and compounds properties like those listed on wiki?  I'd like to find something that I can check numbers against so things like this don't happen. 

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