Symbols for symmetry operators are printed italic, with sub- and super-scripts that are upright except for the variables $k$ and $n$ which are replaced by numbers for a specific operator.
For example:
$E$ – identity operator
$\sigma$ – reflection operator for reflection across a general plane
$\sigma_\mathrm{h}$ – reflection operator for reflection across a horizontal plane
$\sigma_\mathrm{v}$ – reflection operator for reflection across a vertical plane
$C_n{}^k$ – $n$-fold rotation operator for $k$ successive rotations through an angle of $2\pi/n$ about an $n$-fold rotation axis, where $n = 2, 3, \ldots$; $k = 1, 2, \ldots, (n-1)$
$S_n{}^k$ – $n$-fold rotation-reflection operator for $k$ successive rotation-reflections about an $n$-fold rotation-reflection axis for a rotation through an angle of $2\pi/n$ followed
by a reflection in a plane perpendicular to the axis, where $n = 2, 3, \ldots$; $k = 1, 2, \ldots, (n-1)$
$i$ – inversion operator through the centre of symmetry
Likewise,
Symbols for symmetry groups are printed italic with upright subscripts, following common usage.
Symbols for symmetry operators are printed italic, with sub- and super-scripts that are upright except for the variables $k$ and $n$ which are replaced by numbers for a specific operator.
For example: $E$ – identity operator $\sigma$ – reflection operator for reflection across a general plane $\sigma_\mathrm{h}$ – reflection operator for reflection across a horizontal plane $\sigma_\mathrm{v}$ – reflection operator for reflection across a vertical plane $C_n{}^k$ – $n$-fold rotation operator for $k$ successive rotations through an angle of $2\pi/n$ about an $n$-fold rotation axis, where $n = 2, 3, \ldots$; $k = 1, 2, \ldots, (n-1)$ $S_n{}^k$ – $n$-fold rotation-reflection operator for $k$ successive rotation-reflections about an $n$-fold rotation-reflection axis for a rotation through an angle of $2\pi/n$ followedby a reflection in a plane perpendicular to the axis, where $n = 2, 3, \ldots$; $k = 1, 2, \ldots, (n-1)$ $i$ – inversion operator through the centre of symmetry
Likewise,
Symbols for symmetry groups are printed italic with upright subscripts, following common usage.
Notations and conventions used for the description of symmetry in rigid molecules are established in Notations and conventions in molecular spectroscopy: Part 2. Symmetry notation (IUPAC Recommendations 1997):
For example:
$E$ – identity operator
$\sigma$ – reflection operator for reflection across a general plane
$\sigma_\mathrm{h}$ – reflection operator for reflection across a horizontal plane
$\sigma_\mathrm{v}$ – reflection operator for reflection across a vertical plane
$C_n{}^k$ – $n$-fold rotation operator for $k$ successive rotations through an angle of $2\pi/n$ about an $n$-fold rotation axis, where $n = 2, 3, \ldots$; $k = 1, 2, \ldots, (n-1)$
$S_n{}^k$ – $n$-fold rotation-reflection operator for $k$ successive rotation-reflections about an $n$-fold rotation-reflection axis for a rotation through an angle of $2\pi/n$ followed by a reflection in a plane perpendicular to the axis, where $n = 2, 3, \ldots$; $k = 1, 2, \ldots, (n-1)$
$i$ – inversion operator through the centre of symmetry
Likewise,
For example:
$C_n$, $S_{2n}$, $D_n$, $D_{n\mathrm{h}}$, $D_{n\mathrm{d}}$, $C_{n\mathrm{v}}$, $C_{n\mathrm{h}}$, $T$, $T_\mathrm{h}$, $T_\mathrm{d}$, $O$, $O_\mathrm{h}$, $I_\mathrm{h}$, $C_{\infty\mathrm{v}}$, $D_{\infty\mathrm{h}}$
However,
For example:
$\mathrm{A}$, $\mathrm{B}$, $\mathrm{E}$, $\mathrm{A}_1$, $\mathrm{A}_2$
The example table given in the question should thus be typeset as follows:
Notations and conventions used for the description of symmetry in rigid molecules are established in Notations and conventions in molecular spectroscopy: Part 2. Symmetry notation (IUPAC Recommendations 1997):
For example:
$E$ – identity operator
$\sigma$ – reflection operator for reflection across a general plane
$\sigma_\mathrm{h}$ – reflection operator for reflection across a horizontal plane
$\sigma_\mathrm{v}$ – reflection operator for reflection across a vertical plane
$C_n{}^k$ – $n$-fold rotation operator for $k$ successive rotations through an angle of $2\pi/n$ about an $n$-fold rotation axis, where $n = 2, 3, \ldots$; $k = 1, 2, \ldots, (n-1)$
$S_n{}^k$ – $n$-fold rotation-reflection operator for $k$ successive rotation-reflections about an $n$-fold rotation-reflection axis for a rotation through an angle of $2\pi/n$ followedby a reflection in a plane perpendicular to the axis, where $n = 2, 3, \ldots$; $k = 1, 2, \ldots, (n-1)$
$i$ – inversion operator through the centre of symmetry
Likewise,
For example:
$C_n$, $S_{2n}$, $D_n$, $D_{n\mathrm{h}}$, $D_{n\mathrm{d}}$, $C_{n\mathrm{v}}$, $C_{n\mathrm{h}}$, $T$, $T_\mathrm{h}$, $T_\mathrm{d}$, $O$, $O_\mathrm{h}$, $I_\mathrm{h}$, $C_{\infty\mathrm{v}}$, $D_{\infty\mathrm{h}}$
However,
For example:
$\mathrm{A}$, $\mathrm{B}$, $\mathrm{E}$, $\mathrm{A}_1$, $\mathrm{A}_2$
The example table given in the question should thus be typeset as follows:
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