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Is diastereomeric excess sometimes interchanged with enantiomeric excess in publications?
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Kathleen Blake
Is diastereomeric excess sometimes interchanged with enantiomeric excess in publications?
But yes. de and ee imply the same except one is about diastereomers while the other about enantiomers
Blair
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But yes. de and ee imply the same except one is about diastereomers while the other about enantiomers
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James Leland Harp
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There is no endo/exo-isomerism with symmetric fumarates. There is always one substituent being pseudo-axial and one being pseudo-equatorial.
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Jon Dole
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They use the diastereomeric excess here, because they already use enantiomerically pure starting material (the fumarate) to produce a single diastereomer. This is known as chiral auxilliary.
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Joe Belkin
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So no, de and ee are not interchangeable.
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