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Is the SN1 reaction faster with an axial or equatorial leaving group?
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+ Cyclohexane
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Jumana Hasina
Is the SN1 reaction faster with an axial or equatorial leaving group?
In compund 2, both substituents can be placed in equatorial positions, whereas in 1 the $\ce{Cl}$ group is forced into an axial position since the bulky t-butyl group has to be placed equatorial. This makes compound 1 more unstable (higher energy), leading to a faster rate of formation of the carbocation.
In compund 2, both substituents can be placed in equatorial positions, whereas in 1 the $\ce{Cl}$ group is forced into an axial position since the bulky t-butyl group has to be placed equatorial. This makes compound 1 more unstable (higher energy), leading to a faster rate of formation of the carbocation.
In compund 2, both substituents can be placed in equatorial positions, whereas in 1 the $\ce{Cl}$ group is forced into an axial position since the bulky t-butyl group has to be placed equatorial. This makes compound 1 more unstable (higher energy), leading to a faster rate of formation of the carbocation.
In compund 2, both substituents can be placed in equatorial positions, whereas in 1 the $\ce{Cl}$ group is forced into an axial position since the bulky t-butyl group has to be placed equatorial. This makes compound 1 more unstable (higher energy), leading to a faster rate of formation of the carbocation.
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