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Leaving group ability and solvent's effect
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OMONJIATE ELIAB PATRICK
Leaving group ability and solvent's effect
The solvent generally doesn't affect the leaving group ability of an anion. But coming to your Frinkelstein case, it a special one cause here some precipitate is being formed (yes, that's correct that it is due to lower solubility product of say $\ce{NaCl}$ in acetone). As soon as some ppt. is formed, those atoms lose their ionic identity, settle at the bottom and don't interfere in the solvent as solute and so their concentration decreases in the solvent. Due to Le Chatelier's principle, the reaction goes forward to a great extent. This is also the case for other super leaving groups like gases (for eg. $\ce{N2}$, $\ce{H2}$).
The solvent generally doesn't affect the leaving group ability of an anion. But coming to your Frinkelstein case, it a special one cause here some precipitate is being formed (yes, that's correct that it is due to lower solubility product of say $\ce{NaCl}$ in acetone). As soon as some ppt. is formed, those atoms lose their ionic identity, settle at the bottom and don't interfere in the solvent as solute and so their concentration decreases in the solvent. Due to Le Chatelier's principle, the reaction goes forward to a great extent. This is also the case for other super leaving groups like gases (for eg. $\ce{N2}$, $\ce{H2}$).
The solvent generally doesn't affect the leaving group ability of an anion. But coming to your Frinkelstein case, it a special one cause here some precipitate is being formed (yes, that's correct that it is due to lower solubility product of say $\ce{NaCl}$ in acetone). As soon as some ppt. is formed, those atoms lose their ionic identity, settle at the bottom and don't interfere in the solvent as solute and so their concentration decreases in the solvent. Due to Le Chatelier's principle, the reaction goes forward to a great extent. This is also the case for other super leaving groups like gases (for eg. $\ce{N2}$, $\ce{H2}$).
The solvent generally doesn't affect the leaving group ability of an anion. But coming to your Frinkelstein case, it a special one cause here some precipitate is being formed (yes, that's correct that it is due to lower solubility product of say $\ce{NaCl}$ in acetone). As soon as some ppt. is formed, those atoms lose their ionic identity, settle at the bottom and don't interfere in the solvent as solute and so their concentration decreases in the solvent. Due to Le Chatelier's principle, the reaction goes forward to a great extent. This is also the case for other super leaving groups like gases (for eg. $\ce{N2}$, $\ce{H2}$).
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