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Karen J Gray

Reaction of chloroform, resorcinol and strong base

Christine EveningsFall  Follow

Well, turns out to be, the reaction proceeds to product a red colored species.

Reaction with chloroform in the alkaline medium

Dissolve 0.1 g in 1 ml of water R, add 1 ml of strong sodium hydroxide solution R and 0.1 ml of chloroform R, heat and allow to cool. An intense, deep-red colour develops which becomes pale yellow on the addition of a slight excess of hydrochloric acid R.

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Jon Dole  Follow
). Then this carbonyl group electrophilically attacks a second resorcinol molecule to give the dimeric structure.More
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Huang Lu  Follow
Do you know the mechanism of this reaction? I cannot figure it out.More
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Harry Wiliam  Follow
Youre probably looking at a two-part reaction. First chloroform+sodium hydroxide imparts a carbonyl group ortho to a phenolic hydroxyl group (More
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James Leach Jr  Follow
@OscarLanzi probably. I could not find enough evidence to prove that.More
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George White  Follow
see hereMore
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