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Kazakh Wazaky

Resonance Structures of Sulfate Ion

Danilo Angelo  Follow
I got this problem from a multiple choice set that didn't draw out all the lone pairs in the oxygens (which really annoys me), so I don't have much of a choice but to choose from the available choices...

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Charles Tivendale  Follow
Wikipedia: sulfate

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Covid-19  Follow
Some authors suggest that expanded octets are less important contributors to the overall structure than previously thought.  I recall seeing an article in J. Chem. Ed. on this subject some time ago.

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Damian Armata  Follow
Thanks for the response. Does that mean that resonance structures without expanded octets usually contribute more than ones with expanded octets?

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Chr?s Odey  Follow
Doesn't that just mean there's resonance in the sulfate ion?

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Dean Moncaster  Follow
Only your structure A shows all electrons. Choose from other structures that one  with only  two minus charges ( and null charge on sulfur), draw all(!) electrons and all equivalence forms for it.

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Affan Khadir  Follow
Wikipedia somewhat clears things up...thanks!! Is it usually true that resonance structures with expanded octets are less favorable in real life?

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David Hague  Follow
All S-O bonds in crystal structure of sulfates are the same. What does it mean?

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Dawn Walters  Follow
Your structure A shows strictly octet at sulfur atom but many splitted charges.
Your structure C shows 12 electrons around S without no splitted charges. And this is the best - with other mesomeric structures (all 6 - showed in wikipedia)

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