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The mechanism of the reaction between 2-chloroethanol ($\ce{CH2ClCH2OH}$) and hydroxyl ions in aqueous solution forming ethylene oxide ($\ce{CH2CH2)O}$ probably contemplates two steps:
$\ce{CH2ClCH2OH + OH- <=> CH2ClCH2O- + H2O}$
$\ce{CH2ClCH2O- <=> (CH2CH2)O + H2O + Cl-}$
Is the mechanism valid for the following experimental reaction rate?
$\frac{-d[\ce{CH2ClCH2OH}]}{dt} = K_{exp}[\ce{CH2ClCH2OH}][\ce{OH-}]$
2026-10-24