The shift from the origin is due to the solution resistance. If you have higher resistance, you would get more shift from origin. concerning the RC circuit, If you have pure semicircle, you could use the simplified Randles circuit, which is mentioned above. If you have mixed kinetic and diffusion control, you should add a Warburg impedance.
The shift from the origin is due to the solution resistance. If you have higher resistance, you would get more shift from origin. concerning the RC circuit, If you have pure semicircle, you could use the simplified Randles circuit, which is mentioned above. If you have mixed kinetic and diffusion control, you should add a Warburg impedance.
Thank you very much to all
Thank you very much to all
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Dear,
I agree with the above response of Dr. Madani
http://www.bio-logic.info/assets/comm_tutorials/Impedance_II_corrosion.pdf
Dear,
I agree with the above response of Dr. Madani
http://www.bio-logic.info/assets/comm_tutorials/Impedance_II_corrosion.pdf
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Dear Joshi
your equivalent circuit may be a resistance R1 in serie with R2 // C
Dear Joshi
your equivalent circuit may be a resistance R1 in serie with R2 // C
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The shift from the origin is due to the solution resistance. If you have higher resistance, you would get more shift from origin.
concerning the RC circuit, If you have pure semicircle, you could use the simplified Randles circuit, which is mentioned above. If you have mixed kinetic and diffusion control, you should add a Warburg impedance.
The shift from the origin is due to the solution resistance. If you have higher resistance, you would get more shift from origin.
concerning the RC circuit, If you have pure semicircle, you could use the simplified Randles circuit, which is mentioned above. If you have mixed kinetic and diffusion control, you should add a Warburg impedance.
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