Edit: I didn’t notice the upper equation at first because Bad eyes, but as shown, the H2SO4 would be understood to have protonated the CrO3. When the alcohol reacts through O at the Cr atom, generating an intermediate species with a protonated ether, any of HSO4-, H2O or CrO3 could act as base to remove that proton.
Edit: I didn’t notice the upper equation at first because Bad eyes, but as shown, the H2SO4 would be understood to have protonated the CrO3. When the alcohol reacts through O at the Cr atom, generating an intermediate species with a protonated ether, any of HSO4-, H2O or CrO3 could act as base to remove that proton.More
as the others have said, it is a shortcut that indicates a proton (H+) has been abstracted by a base or lone pair elsewhere in the reaction, without having to draw this out. common in reaction mechanisms with a lot of protons being shuttled around, like anything to do with carbonyls/acetals or oxo-metals.
as the others have said, it is a shortcut that indicates a proton (H+) has been abstracted by a base or lone pair elsewhere in the reaction, without having to draw this out. common in reaction mechanisms with a lot of protons being shuttled around, like anything to do with carbonyls/acetals or oxo-metals.More
Like, say, something that could be intramolecular, could be removed by a conjugate base, or could be removed by solvent- and probably is some combination of all of the above in reality.More
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I wonder how most inorganic chemists feel with that Chromium(IV) oxide hydroxide thing.
Always remember that in an acqueous solution H+ leaves the reaction ambient in H3O+ form which is called oxonium ion (basically is protonated water). H2O helps carrying negative and positive charges in a lot of reactions.More
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Unrelated, but what does everyone think of that intramolecular proton transfer?
Unrelated, but what does everyone think of that intramolecular proton transfer?More
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A picture would be better. However I assume it is meant to either describe deprotonation or to describe the 'killing' of (excess) protic species (e.g. via destillation, perception, ...) so that the pH decreases.
A picture would be better. However I assume it is meant to either describe deprotonation or to describe the 'killing' of (excess) protic species (e.g. via destillation, perception, ...) so that the pH decreases.More
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