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Matt Ridings

What will happen when copper will be reacted with hot and concentrated nitric acid?

Bob Fishell  Follow

Copper is an unreactive metal and doesn’t react in normal circumstances with dilute acids. However, it does react with nitric acid. Why is this?

Nitric acid is an oxidizing agent and the reaction is not the usual acid + metal reaction. The products are oxides of nitrogen instead of hydrogen. The actual nitrogen oxide formed depends on the concentration and temperature of the acid.

There are actually two equations for the reaction of copper with nitric acid. It depends on whether the nitric acid is concentrated or not. If it is concentrated and in excess then the ratio is 1:4 copper to nitric acid. If it is dilute then the ratio is 3:8.

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Betsy Morales  Follow

Nitric acid reacts with copper according to the reaction: 4 HNO3(l) + Cu(s) ==> Cu(NO3)2(s and aq) + 2 NO2(g) + 2 H2O(l) The copper nitrate salt that forms is a deep blue color. The nitrogen dioxide is a orange vapor.

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