Home >
Community >
Yellowish tinge during titration of oxalic acid with potassium permanganate
Upvote
26
Downvote
+ Titration
+ Chemistry
+ Redox
Posted by
Liang-Hai Sie
Yellowish tinge during titration of oxalic acid with potassium permanganate
Without knowing the concentrations of the involved substances and the values of some other parameters, we can only guess what has happened during your experiment.
The intended analytical reaction is the reduction of purple permanganate to colourless $\ce{Mn^2+}$:
$$\ce{MnO4- + 8H+ + 5e- <=> Mn^2+ + 4H2O}$$
If you add the permanganate solution too quickly, the reduction may be incomplete because not enough reducing agent (here: oxalic acid) or acid $(\ce{H+})$ is available in the reaction zone:
$$\ce{MnO4- + 4H+ + 3e- <=> MnO2 + 2H2O}$$
The observed colour may be caused by a cloud of finely dispersed particles of dark brown manganese(IV) oxide $(\ce{MnO2})$, which dissolves when the solution is well mixed again so that the intended reaction continues.
The same reaction may occur when you don’t add enough sulfuric acid, since $\ce{H+}$ is consumed during the reaction (8 mol $\ce{H+}$ per 1 mol $\ce{MnO4-}$).
Without knowing the concentrations of the involved substances and the values of some other parameters, we can only guess what has happened during your experiment.
The intended analytical reaction is the reduction of purple permanganate to colourless $\ce{Mn^2+}$:
$$\ce{MnO4- + 8H+ + 5e- <=> Mn^2+ + 4H2O}$$
If you add the permanganate solution too quickly, the reduction may be incomplete because not enough reducing agent (here: oxalic acid) or acid $(\ce{H+})$ is available in the reaction zone:
$$\ce{MnO4- + 4H+ + 3e- <=> MnO2 + 2H2O}$$
The observed colour may be caused by a cloud of finely dispersed particles of dark brown manganese(IV) oxide $(\ce{MnO2})$, which dissolves when the solution is well mixed again so that the intended reaction continues.
The same reaction may occur when you don’t add enough sulfuric acid, since $\ce{H+}$ is consumed during the reaction (8 mol $\ce{H+}$ per 1 mol $\ce{MnO4-}$).
thanks for the explanation. If you need the concentrations, they are as follows: a)20ml of 0.025M Oxalic acid in titration flask(determined by the experiment). b)1 full test tube of 2M sulfuric acid(approx 15ml). c)0.01M KMnO4 in the burette.More
Without knowing the concentrations of the involved substances and the values of some other parameters, we can only guess what has happened during your experiment.
The intended analytical reaction is the reduction of purple permanganate to colourless $\ce{Mn^2+}$:
$$\ce{MnO4- + 8H+ + 5e- <=> Mn^2+ + 4H2O}$$
If you add the permanganate solution too quickly, the reduction may be incomplete because not enough reducing agent (here: oxalic acid) or acid $(\ce{H+})$ is available in the reaction zone:
$$\ce{MnO4- + 4H+ + 3e- <=> MnO2 + 2H2O}$$
The observed colour may be caused by a cloud of finely dispersed particles of dark brown manganese(IV) oxide $(\ce{MnO2})$, which dissolves when the solution is well mixed again so that the intended reaction continues.
The same reaction may occur when you don’t add enough sulfuric acid, since $\ce{H+}$ is consumed during the reaction (8 mol $\ce{H+}$ per 1 mol $\ce{MnO4-}$).
Without knowing the concentrations of the involved substances and the values of some other parameters, we can only guess what has happened during your experiment.
The intended analytical reaction is the reduction of purple permanganate to colourless $\ce{Mn^2+}$:
$$\ce{MnO4- + 8H+ + 5e- <=> Mn^2+ + 4H2O}$$
If you add the permanganate solution too quickly, the reduction may be incomplete because not enough reducing agent (here: oxalic acid) or acid $(\ce{H+})$ is available in the reaction zone:
$$\ce{MnO4- + 4H+ + 3e- <=> MnO2 + 2H2O}$$
The observed colour may be caused by a cloud of finely dispersed particles of dark brown manganese(IV) oxide $(\ce{MnO2})$, which dissolves when the solution is well mixed again so that the intended reaction continues.
The same reaction may occur when you don’t add enough sulfuric acid, since $\ce{H+}$ is consumed during the reaction (8 mol $\ce{H+}$ per 1 mol $\ce{MnO4-}$).
More
VOTE
VOTE