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Electrochromic properties of ethyl viologen
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Abdul Wassay Abbasi
Electrochromic properties of ethyl viologen
[…] I'm very inexperienced with chemistry.
Have a look the material safety datasheet (MSDS) of ethyl viologen dibromide and pay attention to the H-statements:
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
Can you handle this?
You asked:
what to do with it once I have it? I take it there's more to it than just sticking some electrodes in a beaker of it.
It is not that simple.
It is true that 4,4'-dialkyl pyridinium dications undergo a reversible one-electron reduction. This can be achieved by applying a voltage or by electronic excitation in the presence of an electron donor.
However, the resulting radical cations are very sensitive to oxygen and they have been used as probes to monitor oxygen permeation in polymers. With other words, you would have to exclude oxygen from your setup for a lasting colour effect.
In summary, I'd rather advise against the use of ethyl viologen for showcasing, unless the experiments are performed by professionals in a safe environment.
Have a look the material safety datasheet (MSDS) of ethyl viologen dibromide and pay attention to the H-statements:
H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation.
Can you handle this?
You asked:
what to do with it once I have it? I take it there's more to it than just sticking some electrodes in a beaker of it.
It is not that simple.
It is true that 4,4'-dialkyl pyridinium dications undergo a reversible one-electron reduction. This can be achieved by applying a voltage or by electronic excitation in the presence of an electron donor.
However, the resulting radical cations are very sensitive to oxygen and they have been used as probes to monitor oxygen permeation in polymers. With other words, you would have to exclude oxygen from your setup for a lasting colour effect.
In summary, I'd rather advise against the use of ethyl viologen for showcasing, unless the experiments are performed by professionals in a safe environment.
Have a look the material safety datasheet (MSDS) of ethyl viologen dibromide and pay attention to the H-statements:
Can you handle this?
You asked:
It is not that simple.
It is true that 4,4'-dialkyl pyridinium dications undergo a reversible one-electron reduction. This can be achieved by applying a voltage or by electronic excitation in the presence of an electron donor.
However, the resulting radical cations are very sensitive to oxygen and they have been used as probes to monitor oxygen permeation in polymers. With other words, you would have to exclude oxygen from your setup for a lasting colour effect.
In summary, I'd rather advise against the use of ethyl viologen for showcasing, unless the experiments are performed by professionals in a safe environment.
Have a look the material safety datasheet (MSDS) of ethyl viologen dibromide and pay attention to the H-statements:
Can you handle this?
You asked:
It is not that simple.
It is true that 4,4'-dialkyl pyridinium dications undergo a reversible one-electron reduction. This can be achieved by applying a voltage or by electronic excitation in the presence of an electron donor.
However, the resulting radical cations are very sensitive to oxygen and they have been used as probes to monitor oxygen permeation in polymers. With other words, you would have to exclude oxygen from your setup for a lasting colour effect.
In summary, I'd rather advise against the use of ethyl viologen for showcasing, unless the experiments are performed by professionals in a safe environment.
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