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Michael John Spitaletto

Toluene and Water

Ahmed Jawad  Follow
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I wonder if any of them will even come up with azeotrope.

haha... depends on the composition of the class.  Sophomore organic class I would expect a few of them to get it since there should be a few chem majors in there.

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Chux777  Follow
I am over thinking this I guess.  I wonder if any of them will even come up with azeotrope.

Thanks Unassuming

Cheers

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Brett Deese  Follow
Lit has the water/toluene azeotrope at ~80% by mass... so the azeotrope explanation is perhaps right in a way, just not detailed enough of an explanation? 
If they are covering Raoults law in this chapter the answer probably revolves around that.  I would just say that the toluene/water mix is not an ideal gas/liquid so the forces between the two liquids aren't uniform, making it possible for the mol fraction in the gas phase to be different than the liquid.  In the toluene/water case this gives the solution a positive deviation from Raoults law.  I don't know that there is really much else to say, especially for an undergrad organic lab. 

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