Home > Community > Vinegar and baking soda: Cleaning agent or neutralized sludge?
Upvote

26

Downvote
+ Cleaning
Posted by
Mats Petersson

Vinegar and baking soda: Cleaning agent or neutralized sludge?

Char Covelesky  Follow

Well, cleaning is a very broad subject. This is a question which could make a great Science Fair Project. Because vinegar is just a dilute solution of acetic acid (ignoring trace compounds present), and because both baking soda and sodium acetate are pretty soluble, it wouldn't probably be practical to try to make a saturated acidic solution of BS. That is, any precipitates will be made from alkaline solution, under normal circumstances.

There's two questions which would need to be answered:

  1. Does fresh V+BS slurry act the same way as old V+BS slurry?

  2. Are either better than water + BS?

Well, hmm. To be honest, IDK, but I'd guess "maybe" for both (which is why it would be interesting to see what happens). Let me explain:

Acetic acid dissolves soap scum (mostly K, & Ca salts of fatty acids) and dissolves water hardness (mostly Ca & Mg carbonates) So starting off getting rid of some or all of that junk could definitely be a good thing (and acetic acid is only going to be around for a very short time if BS is present in excess). But we know that acids attack metals, so leaving vinegar on metal isn't a good idea...and guess what? Once the BS fully reacts, the acid will be gone! I can't think of any other plausible reason that V+BS would be better than W+BS.

One other potential reason would be if the vinegar changed the abrasiveness of the BS, making it more effective (which is another thing you could test for), but I doubt it would. (possible but not quite plausible, if you know what I mean). Anyway, what you've got left is W+BS after the reaction, so what's the worst it can do?

I do know for sure that most cleaners (with the exception of many metal cleaners) are alkaline because higher pH tends to dissolve (and/or lift-off (which means form a colloid of or weaken the adhesion to the surface-to-be-cleaned of)) organics better than acidic solutions. Cleanser, which is usually just mostly silica, certainly is more abrasive than BS, but that also means it will tend to scratch (or fog) more surfaces. I don't know, but I'll bet most cleansers are alkaline for the reason mentioned above. (alkaline solutions are NOT more slippery, but they form soaps out of your skin, and those soaps are more slippery. So, the slipperiness you feel when you touch an alkaline (basic) solution is just your skin dissolving :)

More

Upvote

VOTE

Downvote
Jimswen  Follow
Ill also note that water hardness is the sum of the concentrations of calcium and magnesium in their aqueous (ionic) states (carbonates are usually the source, but the definition of hardness is incorrect); and that bases (not acids) are used to precipitate the hydroxide salts of calcium and magnesium. The acid will dissolve the solid carbonate species, but you have to get rid of the calcium/magnesium.More
Upvote

VOTE

Downvote
James Stewart  Follow
, youd see that were not like conventional forums, and in the "answer" part, only actual answers to the question go, not commentary about the question.More
Upvote

VOTE

Downvote
Forrest Frost  Follow
Hello Li Zhi, and welcome to Chemistry Stack Exchange. If you take a More
Upvote

VOTE

Downvote
Andrei Tancau  Follow

One application of baking soda and vinegar is in cleaning a glass stovetop. You start with baking soda and water. The dissolved baking soda acts as a base, and the undissolved baking soda acts as mild abrasive.

Once you are done cleaning, you need to get rid of the baking soda, and might want to adjust the pH of the cleaned surface. So at this point, you can add vinegar, which reacts with the baking soda to yield sodium acetate, which is soluble in water.

$$\ce{NaHCO3(s) + CH3COOH(aq) -> Na+(aq) + CH3COO-(aq) + CO2(g) + H2O(l)}$$

This only works if you use baking soda by itself first, and then add the vinegar once the dirt is already off the stovetop.

More

Upvote

VOTE

Downvote