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Polymethylene Polyphepylene lsocyanate, PMDI, M20S BASF, Cas No.: 101-68-8

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CAS No.:

101-68-8

Grade:

Industrial Grade

Content:

99%

Port:

Qingdao

Brand:

Qichen

Packaging:

250KG/DRUM or 1250KG/IBC

Price valid (until):

2025-12-31

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Qichen Chemicals

Company Type:

Manufactory

Location:

China

Qualification:

Main Products:

Fine chemicals,Oilfield drilling chemicals,Polyurethane raw materials,Basic chemicals

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Product Description
Seller Information
Inquiry History

Description

Polymeric Methylene Diphenyldiisocyanate ( PMDI)

Polymeric MDI 99%

Cas:9016-87-9

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Introduction:

Polymeric Methylene Diphenyldiisocyanate (PMDI) is a brown mixture of monomeric (2-ring) and polyaromatic （3-ring and higher species) Methylene Diphenyldiisocyanates, which is liquid at room temperature. It is mainly used in producing Polyurethane rigid foam as Part B in two-component system. The Part A is blended polyols formulated as requirement of application, with catalyst, silicone, flame retardant and blowing agent.

Specific Application:

1. Rigid foam (used for thermal insulation)

Refrigerator industry

Water heater, solar energy

Panel （used for cold storage and insulated doors, etc.）

Pipes （underground hot water pipes, etc.）

Spray foam（used on exterior walls，cold storage etc.)

Refrigerated container

Door body and packaging materials

OCF (one-component caulking agent)

2.Reflexible foam

Large sponge T/M 80/20 (ratio of TDI and MDI)

Self-skinning T/M (coarse MDI) 50/50

3.Curing agent

Woodworking glue

Casting elastomer

Coating

Packing & Delivery

250KG/DRUM
1250KG/IBC

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Company Profile：

Qichen Chemical (Tianjin) Co., Ltd. was established in the year of 2012. Our factory is located in Zhanhua District, Binzhou City, Shandong Province，where is the birthplace of China chemical industry. The factory covers an area of more than 13,000 square meters, with annual output about 50,000 tons and storage capacity about 1500 square meters. We're engaged in researching, producing and sales of raw materials of Polyurethane, fine chemicals, basic chemicals and oilfield drilling chemicals. Along with 10-year development, we have already set up offices and warehouses in Tianjin, Qingdao, Linyi, Zibo, Zhengzhou, etc. We also have long-term partners, which could give rapid delivery for our customers. Our mission is always focused on our passion to meet the needs of our clients wih cost-effective products ,convenient and feasible solutions.

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Certificates

Basic Info

Product Name:

Diphenylmethane diisocyanate

Other Name:

Benzene,1,1′-methylenebis[4-isocyanato-;Isocyanic acid,methylenedi-p-phenylene ester;1,1′-Methylenebis[4-isocyanatobenzene];Bis(4-isocyanatophenyl)methane;Diphenylmethane 4,4′-diisocyanate;Methylenebis(4-isocyanatobenzene);Bis(p-isocyanatophenyl)methane;p,p′-Methylenebis(phenyl isocyanate);4,4′-Methylenebis(phenyl isocyanate);Methylenebis(4-phenyl isocyanate);Diphenylmethylene 4,4′-diisocyanate;Methylenedi-p-phenylene diisocyanate;Methylenedi-p-phenylene isocyanate;4,4′-Methylenediphenyl diisocyanate;4,4′-Diisocyanatodiphenylmethane;Methylenebis(p-phenylene isocyanate);Methylbis(4-phenylisocyanate);4,4′-Methylenediphenylene isocyanate;Methylenebis(4-phenylene isocyanate);Methylenebis(p-phenyl isocyanate);Bis(1,4-isocyanatophenyl)methane;MDI;Methylenebis-p-phenylene diisocyanate;Methyldi-p-phenylene isocyanate;4,4′-Diphenylmethane diisocyanate;p,p′-Diphenylmethane diisocyanate;4,4′-Methylenedi-p-phenylene diisocyanate;Diisocyanatodiphenylmethane;Methylenebis(phenyl isocyanate);Diphenylmethane diisocyanate;Di(4-isocyanatophenyl)methane;4,4′-Methylenebis(isocyanatobenzene);Methylenebisphenylene diisocyanate;4,4′-MDI;Isocyanic acid,diphenylmethylene ester;Diphenylmethylene diisocyanate;4,4′-Methylenedi(phenyl isocyanate);4,4′-Bis(isocyanatophenyl)methane;Methylene diphenyl diisocyanate;NSC 9596;Diphenylmethyl diisocyanate;Methylene diisocyanate;Bis(isocyanatophenyl)methane;53633-14-0;55157-41-0;57460-66-9;77090-48-3;88001-94-9;97568-33-7;142690-07-1;153986-89-1;201528-77-0;1211266-59-9;1211316-64-1;1220313-65-4;1400594-70-8;1533423-48-1;1588489-56-8;2031250-39-0;2056146-02-0

CAS No.:

101-68-8

Molecular Formula:

C15H10N2O2

InChIKeys:

InChIKey=UPMLOUAZCHDJJD-UHFFFAOYSA-N

Molecular Weight:

250.25200

Exact Mass:

250.25

EC Number:

202-966-0

HScode:

29291090

Categories:

Polymer

Characteristics

PSA:

58.86000

XLogP3:

3.21200

Appearance:

Diphenylmethane-4,4-diisocyanate is a light yellow colored solid. It is not soluble in water. It may be toxic by ingestion, inhalation, or skin absorption. If in a solution it may or may not burn depending on the nature of the material and/or the solvent. It is used to make plastics.

Density:

1.197 g/cm³ @ Temp: 70 °C

Melting Point:

37 °C

Boiling Point:

196 °C @ Press: 5 Torr

Flash Point:

196ºC

Refractive Index:

1.5906 (50ºC)

Water Solubility:

Decomposes in water

Storage Conditions:

Refrigerator

Vapor Pressure:

9.02E-06mmHg at 25°C

Vapor Density:

Relative vapour density (air = 1): 8.6

Flammability characteristics:

Combustible Solid

Odor:

Odorless

See More Diphenylmethane diisocyanate Properties 

Hazard Identification

Classification of the substance or mixture

Skin irritation, Category 2

Eye irritation, Category 2

Skin sensitization, Category 1

Acute toxicity - Category 4, Inhalation

Specific target organ toxicity â single exposure, Category 3

Respiratory sensitization, Category 1

Carcinogenicity, Category 2

Specific target organ toxicity â repeated exposure, Category 2

GHS label elements, including precautionary statements

Precautionary statement(s)
Pictogram(s)
Signal word	Danger
Hazard statement(s)	H315 Causes skin irritation H319 Causes serious eye irritation H317 May cause an allergic skin reaction H332 Harmful if inhaled H335 May cause respiratory irritation H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure
Prevention	P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P271 Use only outdoors or in a well-ventilated area. P284 [In case of inadequate ventilation] wear respiratory protection. P203 Obtain, read and follow all safety instructions before use. P260 Do not breathe dust/fume/gas/mist/vapours/spray.
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P317 If skin irritation occurs: Get medical help. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P317 If skin irritation or rash occurs: Get medical help. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P317 Get medical help. P319 Get medical help if you feel unwell. P342+P316 If experiencing respiratory symptoms: Get emergency medical help immediately. P318 IF exposed or concerned, get medical advice.
Storage	P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal	P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

Handling and Storage

Precautions for safe handling

NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Cool. Dry. Keep in the dark.Isocyanates are transported in railroad tank cars, tank trucks, tanks in ships, containers, and drums. They are stored in steel tanks and processed in steel equipment. For long-term storage stainless steel is recommended. To avoid contamination by atmospheric moisture, a dry air or inert gas blanket is essential. Isocyanates

See More Diphenylmethane diisocyanate Safety Data Sheet 

Seller Information

Business Type:
Manufactory

Main Products:
Fine chemicals,Oilfield drilling chemicals,Polyurethane raw materials,Basic chemicals

Location:
shandong，BInzhou

Payment Terms:
TT against copy of documents,L/C,TT against B/L draft before shipment,100% TT in advance

Average lead Time:
15

Total Annual Revenue:
$1 million-$2.5 million

Total Employees:
11-50

Year of Establishment:
2014

Qichen was established in the year of 2012. Our producing plant is located in Zhanhua District, Binzhou City, Shandong Province where is birthplace of China chemicals. The producing plant covers an area of more than 13,000 square meters, with annual output about 50,000 tons production and 1500M³ storage of polyurethane raw materials. We are committed to providing the research, producing and construction service of polyether polyols and rigid blended polyols, etc.. Along with 10 years development, we have already set up offices and warehouses in Tianjin, Qingdao, Linyi, Zibo, Zhengzhou, etc. which could give rapid delivery for our customers. Based on the development of polyurethane raw material series, Qichen has expanded business scope to fine chemicals, basic chemicals and oilfield drilling chemicals in recent years.

Binzhou city comes with rich industrial support, such as advanced technical resources, abundant material supply, huge production and storage capacity, all of which are leading in China. If coming into this city, you could get any you want for chemical industries.

Qichen will continue to innovate in the field of chemical new materials, lead the development of the chemical industry, and create a better life for mankind.

Inquiry History

24 Inquiries

Country	Product	Purchase Quantity	Date Posted
United Arab Emirates	(MDI) Methylene Diphenyl Diisocyanate	1.00 KG	Mar 5, 2026
Qatar	4’-diphenylmethane diisocyanate	10.00 KG	Sep 15, 2025
Mexico	Monomeric Methylene diphenyl Diisocyanate	20000 KG	May 16, 2025
United Arab Emirates	Methylene Diphenyl Diisocyanate	2.00 20' Fcl	Dec 30, 2024
India	4,4 MDI (Equivalent to Lupranate MI and Desmodur 2460)	1000.00 KG	Dec 6, 2024
United Arab Emirates	(MDI) Methylene Diphenyl Diisocyanate	1.00 KG	Jun 2, 2026
India	Methylene diphenyl diisocyanate	5.00 20' Fcl	Mar 3, 2026
India	methylene bis(4-phenylisocyanate)	500 G	Jul 21, 2025
Saudi Arabia	Methylene diphenyl diisocyanate	1.00 20' Fcl	Apr 23, 2025
India	MDI	27 MT	Mar 4, 2025
South Africa	Methylene diphenyl diisocyanate	1.00 MT	Jul 19, 2024
Slovenia	MMDI	5 MT	Dec 5, 2023
Chile	4,4'-Diphenylmethane diisocyanate 99% solid	3500 L	Nov 3, 2023
Hongkong, China	MDI	200 MT	Oct 23, 2023
Poland	Methylene diphenyl diisocyanate	250.00 KG	May 15, 2026
United Arab Emirates	(MDI) Methylene Diphenyl Diisocyanate	1.00 KG	Apr 16, 2026
United Arab Emirates	Methylene Diphenyl Diisocyanate	1.00 40' Fcl	Aug 20, 2025
India	Diphenyl Methane-4,4'-Diisocyanate (MDI)	250 MT	Jul 31, 2025
Saudi Arabia	Methylene Diphenyl Diisocyanate	1.00 20' Fcl	Dec 31, 2024
Saudi Arabia	Methylene Diphenyl Diisocyanate	1.00 20' Fcl	Dec 24, 2024

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