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Trimethylolpropane triacrylate 15625-89-5

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Unit Price: Get Latest Price
CAS No.:

15625-89-5

Grade:

Industrail Grade

Content:

99%

Port:

SHANGHAI

Brand:

Orient

Packaging:

25L, 200L, 1000L, customized

Price valid (until):

2026-01-16

Company Type:
Trader
Location:
China
Qualification:
Main Products:

pharmaceutical intermediates,peptides,electronic chemicals

  • Product Description

  • Seller Information

  • Inquiry History

  • Description
    Product Name: Trimethylolpropane triacrylate
    Synonyms: 1,1,1-(TRIHYDROXYMETHYL)PROPANE TRIACRYLATE;1,1,1-TRIMETHYLOL PROPANE TRIACRYLATE;2-propenoic acid 2-ethyl-2-[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester;2-ETHYL-2-(HYDROXYMETHYL)-1,3-PROPANEDIOL TRIACRYLATE;2-Ethyl-2-[[(1-oxoallyl)oxy]methyl]-1,3-propanediyl diacrylate;TMPTA;TRIMETHYLOLPROPANE TRIACRYLATE;HEXAGLYCERINE TRIACRYLATE
    CAS: 15625-89-5
    MF: C15H20O6
    MW: 296.32
    EINECS: 239-701-3
    Product Categories: Functional Monomer;15625-89-5
    Mol File: 15625-89-5.mol
    Shop Trimethylolpropane triacrylate 15625-89-5-Detailed Image 1

    Trimethylolpropane triacrylate Chemical Properties
    Melting point  -66°C
    Boiling point  >200°C
    density  1.1 g/mL at 25 °C (lit.)
    vapor density  >1 (vs air)
    vapor pressure  <0.01 mm Hg ( 20 °C)
    refractive index  n20/D 1.474(lit.)
    Fp  >230 °F
    storage temp.  Refrigerator
    pka 0[at 20 ℃]
    form  Liquid
    color  Colorless to Light yellow to Light orange
    Specific Gravity 1.1
    Water Solubility  Miscible with water.
    FreezingPoint  -66
    InChIKey DAKWPKUUDNSNPN-UHFFFAOYSA-N
    LogP 4.35 at 20℃
    CAS DataBase Reference 15625-89-5(CAS DataBase Reference)
    IARC 2B (Vol. 122) 2019
    NIST Chemistry Reference TMPTA (Trimethylol propane triacrylate)(15625-89-5)
    EPA Substance Registry System Trimethylolpropane triacrylate (15625-89-5)

    Safety Information
    Hazard Codes  Xi
    Risk Statements  36/38-43
    Safety Statements  39
    WGK Germany  1
    RTECS  AT4810000
    TSCA  Yes
    HS Code  29161290
    Hazardous Substances Data 15625-89-5(Hazardous Substances Data)
    Toxicity LD50 oral in rat: 5190uL/kg
    MSDS Information

    Trimethylolpropane triacrylate Usage And Synthesis
    Description Trimethylolpropane triacrylate (TMPTA) is a multifunctional acrylie monomer. It reacts with propyleneimine to form polyfunctional aziridine. Sensitization was observed in a textile fabric printer. Patch tests were positive with the polyfunctional aziridine hardener, but were negative to TMPTA. TMPTA caused contact dermatitis in an optic-fiber manufacturing worker and was reported as a sensitizer in a floor top coat or in photopolymerizable inks.
    Chemical Properties Colorless viscid liquid
    Uses Trimethylol propane triacrylate is a triacrylate for use in UV -curable lithographic inks, varnishes, artificial nails, wood finish solder, and etch resists in the electronics industry.
    Uses Trimethylolpropane triacrylate has important properties like low volatility, resistance against weather, chemical, water and abrasion, and immediate curing property. The above mentioned properties prompted its use in the production of adhesives, plastics, sealant chemicals, paint additives, photosensitive chemicals, ink and toner. It finds application in alkyd coatings, dental polymers, compact discs, hardwood floors, concrete polymers, screen printing, elastomers, automobile headlamps, acrylics and plastic components for the medical industry.
    Preparation Synthesis of trimethylolpropane triacrylate: 2.44 kg of trimethylolpropane, 3.93 kg of acrylic acid, 0.5 kg of an acid ion exchanger (Lewatit 3333 of BAYER AG), 9 g of hydroquinone and 1.5 liters of petroleum ether (boiling range 60° to 70° C) were heated under a water separator, whilst stirring, in a 10 liter three-necked flask equipped with a stirrer, water separator and gas inlet tube. At the same time, a constant stream of air saturated with allyl alcohol was passed through the flask at a rate of 2 liters/hour. In total, 16 ml of allyl alcohol were introduced into the esterification mixture in this way. After 80 hours, the reaction mixture had an acid number of 32 and the boiling point had risen to 72° C. The petroleum ether was distilled off, remnants being removed by applying a vacuum of 0.2 mm Hg at a product temperature of 40° C. The esterification catalyst was separated off by filtration and was kept for further use. The trimethylolpropane triacrylate obtained in practically quantitative yield was pale yellowish and clear. The viscosity corresponded to a time of outflow of 20 seconds measured in a DIN cup 4 at 20° C. The product showed no change even on storage for 4 months at 60° C. When used in a UV light-curing printing ink which contained a photoinitiator, the product polymerised at high speed.
    Literature source US04059721

    First aid measures

    If inhaled

    Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.

    Following skin contact

    Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.

    Following eye contact

    Rinse with pure water for at least 15 minutes. Consult a doctor.

    Following ingestion

    Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.

    Accidental release measures


    Personal precautions, protective equipment and emergency procedures

    Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak. Environmental precautions

    Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up

    Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.

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    ——  Q&A  ——

    Q1:Do you provide sample?

    A: Yes, we can provide free sample, you only need pay the shipping cost.

    Q2: What is the lead time?

    A: For stock goods, it usually take about 5-7 days by air, 15-30 days by sea,For customized products, the delivery time needs to be confirmed based on the actual situation.

    Q3: How can I buy? What is the payment method?

    A: You can contract us through Email or you can browse our website:orientchem.cc, we have bank transfer, 

    Q4:What if there are quality issues?

    A:We attach great importance to after-sales service of our products. If there are any quality issues, please contact us within 30 days of receiving the goods and we will handle returns and exchanges for you.



    Certificates

    Basic Info
    Product Name:

    Trimethylolpropane triacrylate

    Other Name:

    2-Propenoic acid,1,1′-[2-ethyl-2-[[(1-oxo-2-propen-1-yl)oxy]methyl]-1,3-propanediyl] ester;Acrylic acid,triester with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol;2-Propenoic acid,2-ethyl-2-[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester;1,3-Propanediol,2-ethyl-2-(hydroxymethyl)-,triacrylate;Trimethylolpropane triacrylate;SR 351;Sartomer SR 351;NK Ester A-TMPT;Monocizer TD 1500A;Viscoat 295;Setalux UV 2241;A-TMPT;Aronix M 309;Kayarad TMPTA;TMPTA;Light Acrylate TMP-A;2-Ethyl-2-(hydroxymethyl)-1,3-propanediol triacrylate;TMP 3A;Ageflex TMPTA;Saret 351;M 309;Blemmer ATT;TD 1500A;Sartomer 357;Sartomer 351;M 308;Aronix M 308;Newfrontier TMPT;M 380;Kayarad KS-TMPTA;Neomer TA 300;Photomer 4006;SR 351HP;Aronix M 709;TMPTA-N;KS-TMPTA;TMP 3A3;Laromer TMPTA;V 295;M 300;Genomer 1330;T 30;Etermer 231;SR 351H;SR 351LV;Photomer 4006F;SR 351S;Miramer M 300;TMP-A;SR 519HP;Ebecryl TMPTA;Viscoat V 295;Kayarad M 309;EM 231;SM 631;SR 315S;Viscoat PET-S;EM 231TF;Miramer 300;SR 351NS;Etermer EM 231;SR 354;SR 454D-NS;1,1,1-Tri(acryloyloxymethyl)propane;LM 353;Saret SR 519HP;Cognis 4006;CLM 400;Sartomer 351HP;2,2-Bis[(acryloyloxy)methyl]butyl acrylate;AgiSyn 2811;EM 232;PL 400;2,2-Bis(prop-2-enoyloxymethyl)butyl prop-2-enoate;SR 305;Viscoat TMP 3A;Laromer PR 9119;58998-51-9;72269-91-1;100465-65-4;116335-81-0;117079-82-0;159251-16-8;162193-38-6;199685-35-3;255831-11-9;352031-28-8;1186622-07-0;1199921-30-6;1325731-65-4;1798797-17-7

    CAS No.:

    15625-89-5

    Molecular Formula:

    C15H20O6

    InChIKeys:

    InChIKey=DAKWPKUUDNSNPN-UHFFFAOYSA-N

    Molecular Weight:

    296.319

    Exact Mass:

    296.32

    EC Number:

    239-701-3

    UNII:

    4B67KGL96S

    DSSTox ID:

    DTXSID0027773

    Color/Form:

    Viscous, colorless to tan liquid

    HScode:

    29161290

    Characteristics
    PSA:

    78.9

    XLogP3:

    2.75

    Appearance:

    Liquid

    Density:

    1.11 g/cu cm at 20 deg C

    Melting Point:

    -66°C

    Boiling Point:

    >100 °C

    Flash Point:

    >230 °F

    Refractive Index:

    n 20/D 1.474(lit.)

    Water Solubility:

    Insoluble in water

    Storage Conditions:

    Refrigerator

    Vapor Pressure:

    <0.01 mm Hg ( 20 °C)

    Vapor Density:

    >1 (vs air)

    Toxicity:

    LD50 oral in rat: 5190uL/kg

    Odor:

    Acrylic or pungent odor

    Henrys Law Constant:

    Henry's Law constant = 6X10-10 atm-cu m/mol at 25 °C (est)

    Experimental Properties:

    Hygroscopic, light sensitive, and incompatible with strong oxidizing agents, acids, and bases; may undergo spontaneous polymerization when exposed to direct sunlight and heat|Hydroxyl radical reaction rate constant = 3.4X10-11 cu cm/molecule-sec at 25 °C (est)

    Hazard Identification

    Classification of the substance or mixture

    Skin irritation, Category 2

    Eye irritation, Category 2

    Skin sensitization, Category 1

    GHS label elements, including precautionary statements

    Pictogram(s)
    Signal word

    Warning

    Hazard statement(s)

    H315 Causes skin irritation

    H319 Causes serious eye irritation

    H317 May cause an allergic skin reaction

    Precautionary statement(s)
    Prevention

    P264 Wash ... thoroughly after handling.

    P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

    P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

    P272 Contaminated work clothing should not be allowed out of the workplace.

    Response

    P302+P352 IF ON SKIN: Wash with plenty of water/...

    P321 Specific treatment (see ... on this label).

    P332+P317 If skin irritation occurs: Get medical help.

    P362+P364 Take off contaminated clothing and wash it before reuse.

    P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

    P333+P317 If skin irritation or rash occurs: Get medical help.

    Storage

    none

    Disposal

    P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

    Other hazards which do not result in classification

    no data available

    Handling and Storage

    Precautions for safe handling

    Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

    Conditions for safe storage, including any incompatibilities

    Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.

  • Seller Information
    Business Type:

    Trader

    Main Products:

    pharmaceutical intermediates,peptides,electronic chemicals

    Location:

    Room 102, 1st Floor, East Office Building, No. 45 Pengwan Road, Qianwan Bonded Port Area, Qingdao Zone, China (Shandong) Pilot Free Trade Zone

    Payment Terms:

    100% TT in advance

    Average lead Time:

    10

    Total Annual Revenue:

    $10 million-$25 million

    Total Employees:

    51-100

    Year of Establishment:

    2024

    A reliable supplier is like insurance.

    We are mainly specilized in supply of pharmaceutical intermediates, electronic chemicals,food additives, and other fine chemical products.
    Integrity is the foundation, quality is life. We would like to work together with you to build a greener and brighter future.

    Website: orientchem.cc
    Email: scarlett@orientchem.cc
    WhatsApp: +86 17753254221

  • Inquiry History
    5 Inquiries
    Country Product Purchase Quantity Date Posted
    India

    TRIMETHYLOLPROPANE TRIACRYLATE

    8 MT Sep 27, 2023
    India

    Trimethylolpropane Triacrylate

    24 MT Jun 2, 2026
    Bangladesh

    Trimethylolpropane Triacrylate

    10 TON Oct 15, 2024
    India

    Trimethylolpropane triacrylate

    10 MT Mar 14, 2024
    India

    TRIPROPYLENE GLYCOL DIACRYLATE (TPGDA)

    4 MT Sep 27, 2023
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