Lithium tri-sec-butylborohydride
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Lithium tri-sec-butylborohydride
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CAS No:
38721-52-7
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Formula:
C12H28B.Li
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Chemical Name:
Lithium tri-sec-butylborohydride
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Synonyms:
Borate(1-),hydrotris(1-methylpropyl)-,lithium (1:1),(T-4)-;Borate(1-),hydrotris(1-methylpropyl)-,lithium,(T-4)-;Lithium tri-sec-butylborohydride;L-Selectride;Lithium tri-sec-butylhydroborate(1-);Lithium tris(sec-butyl)borohydride;Lithium selectride;Lithium hydrotri-s-butylborate;Lithium tris(s-butyl)hydroborate(1-);Lithium tri(s-butyl)borohydride
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CAS No:
Characteristics
4.88150
Colorless to yellow Liquid
0.89 g/mL at 25 °C
1 °F
Solubility in water: reaction.;Miscible with tetrahydrofuran.
Flammables area
Safety Information
II
4.3
UN 3394 4.2/PG 1
1
11-14/15-17-34-35-19-40-37
16-26-36/37/39-43-45-7/8-30
F,C
Lithium tri-sec-butylborohydride Use and Manufacturing
Reducing agent. Reagent for: Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters. Diastereoselective reduction reactions. Hydride reduction of the Danishefsky pyranones. Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes. Synthesis of alkanols by carbonylation reactions.
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Lithium tri-sec-butylborohydride
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