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Home > Encyclopedia > Nickel iodide (NiI2)

Nickel iodide (NiI2)

Nickel iodide (NiI2) structure

Nickel iodide (NiI2) 

structure
  • CAS No:

    13462-90-3

  • Formula:

    I2Ni

  • Chemical Name:

    Nickel iodide (NiI2)

  • Synonyms:

    Nickel iodide (NiI2);Nickelous iodide;Nickel diiodide;Nickel(2+) iodide;Nickel iodide

  • Categories:

    Inorganic Chemistry  >  Inorganic Salts

Nickel iodide (NiI2) Basic Attributes

312.5

311.744263

236-666-6

DTXSID1065479

Iron-black color

Characteristics

0

1.77140

black Powder

5.834 g/cm3

780 °C

soluble in water and alcohols.

LOSES WATER AT 43 °C /HEXAHYDRATE/|Sublimes in absence of air|Bluish green crystals /Hexahydrate/|Very soluble in water or alcohol /Hexahydrate/|Hygroscopic; sublimes at 797 °C without melting /Hexahydrate/

Safety Information

III

6.1(b)

UN 3260 8/PG 2

3

45-61-42/43

53-22-26-36/37/39-45

T

P201-P261-P273-P280-P284-P304 + P340

H317-H334-H341-H350i-H360D-H372-H410

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

A MIXTURE OF POTASSIUM & ... /NICKEL IODIDE/ PRODUCES A STRONG EXPLOSION ON IMPACT ... .

|Danger|H317 (100%): May cause an allergic skin reaction [Warning Sensitization, Skin]|P201, P202, P260, P261, P264, P270, P272, P273, P280, P281, P285, P302+P352, P304+P341, P308+P313, P314, P321, P333+P313, P342+P311, P363, P391, P405, and P501|Aggregated GHS information provided by 42 companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Vacated 1989 OSHA PEL TWA 0.1 mg/cu m is still enforced in some states. /Nickel soluble compounds, as Ni/|Permissible Exposure Limit: Table Z-1 8-hr Time Weighted Avg: 1 mg/cu m. /Nickel, soluble cmpd, as Ni/

NIOSH considers nickel metal and other compounds (as Ni) to be a potential occupational carcinogen. /Nickel metal and other compounds (as Ni)/|NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. /Nickel metal and other compounds (as Ni)/|Recommended Exposure Limit: 10 Hr TWA 0.015 mg/cu m. /Nickel metal and other compounds (as Ni)/

Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Nickel iodide is included on this list.

Drug Information

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilation if necessary. Administer oxygen by nonrebreather mask at 10 t0 15 L/min. Monitor for shock and treat if necessary ... . Monitor for pulmonary edema and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . /Nickel and related compounds/|Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious. Positive pressure ventilation techniques with a bag valve mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Consider drug therapy for pulmonary edema ... . Start an IV with D5W /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors for hypotension with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Nickel and related compounds/

Nickel iodide (NiI2) Use and Manufacturing

Methods of Manufacturing

Direct combination of nickel and iodide.|/Reacting/ hydroiodic acid with nickel carbonate yields nickel iodide. /Nickel iodide hexahydrate/

Uses

Strongly accelerates Sml2 mediated homocoupling of imines into vicinal diamines and heterocoupling reactions between imines and ketones.1

-60 mesh, 99.5% purity grade

Nickel iodide (NiI2): ACTIVE

Computed Properties

Molecular Weight:312.502
Exact Mass:311.74429
Monoisotopic Mass:311.74429
Heavy Atom Count:3
Complexity:2.8
Covalently-Bonded Unit Count:1
Compound Is Canonicalized:Yes

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